344873-94-5Relevant academic research and scientific papers
STEREOSELECTIVE PERACID EPOXIDATION OF ALLYLIC AND δ-HYDROXYALLYLIC DIPHENYLPHOPHINE OXIDES
McElroy, Andrew B.,Warren, Stuart
, p. 2119 - 2122 (1985)
The title compounds were epoxidised by m-chloroperbenzoic acid with high stereoselectivity induced by the Ph2PO or hydroxyl groups.
Synthesis of β-(Diphenylphosphinoyl) Ketones
Bell, Andrew,Davidson, Alan H.,Earnshaw, Chris,Norrish, Howard K.,Torr, Richard S.,et al.
, p. 2879 - 2892 (2007/10/02)
The title compounds may be made by addition of phosphorus nucleophiles (Ph2PO-, Ph2POMgX, Ph2PCl) to enones, by addition of phosphorus-stabilised carbanions to a α-carbonyl cation equivalents (2,3-dichloropropene, epoxides, and α-MeO-ketones) and by oxidation of allyl diphenylphosphine oxides.
