345211-69-0Relevant academic research and scientific papers
Diversity-oriented synthesis of substituted furo[2,3-b]pyrazines
Mehta, Vaibhav P.,Modha, Sachin G.,Ermolat'Ev, Denis,Van Hecke, Kristof,Van Meervelt, Luc,Van Der Eycken, Erik V.
experimental part, p. 27 - 41 (2009/07/25)
A highly efficient method for the synthesis of diversely substituted furo[2,3-b]pyrazines has been elaborated. The Ag+- or iodine-mediated electrophilic cyclization of readily generated 5-chloro-3-substituted ethynyl-1-(4-methoxybenzyl)-pyrazin-2(1H)-ones affords substituted furo[2,3-b]pyrazines, which undergo various palladium catalyzed reactions to generate a library of difficult to attain diversely substituted furo[2,3-b]pyrazines. CSIRO 2009.
FREMY'S SALT OXIDATION OF BENZYLAMINES. AN OXIDATIVE DEAMINATION REACTION
Castedo, Luis,Riguera, Ricardo,Rodriguez, M. Jesus
, p. 1569 - 1570 (2007/10/02)
Fremy's salt is shown to oxidize efficiently primary benzylamines to imines, benzaldehydes and nitriles.
