345231-53-0Relevant academic research and scientific papers
Unique property of copper(I) chloride as a radical initiator as well as a Lewis acid: Application to CuCl-catalyzed aldol reaction of α,β- unsaturated ketones with Bu3SnH
Ooi, Takashi,Doda, Kanae,Sakai, Daiki,Maruoka, Keiji
, p. 2133 - 2136 (2007/10/03)
Copper (I) chloride in combination with tributyltin hydride showed unique character as an initiator of certain radical reactions. Hydrostannation of α,β-unsaturated ketones with Bu3SnH was initiated by CuCl and the resulting tin enolates underwent subsequent aldol reaction with aldehydes under the influence of CuCl as a Lewis acid catalyst.
A NEW ALDOL REACTION: A METHOD FOR THE GENERATION OF VINYLOXYBORANES BY THE ACYLATION OF BORON-STABILIZED CARBANIONS
Mukaiyama, Teruaki,Murakami, Masahiro,Oriyama, Takeshi,Yamaguchi, Masahiko
, p. 1193 - 1196 (2007/10/02)
Phenyl-substituted vinyloxyboranes are generated by the acylation of boron-stabilized carbanions with methyl benzoate.Vinyloxyboranes thus generated further react with aldehydes to give the corresponding cross-aldols in good yields.
