34535-98-3

Basic information

• Product Name: N-Cyclopropylaniline
• Synonyms: N-Cyclopropylaniline
• CAS NO: 34535-98-3
• Molecular Formula: C₉H₁₁N
• Molecular Weight: 133.19034
• Mol File: 34535-98-3.mol
• Article Data: 20

Chemical Properties

• Appearance: /
• Storage Temp.: 2-8°C(protect from light)
• CAS DataBase Reference: N-Cyclopropylaniline(CAS DataBase Reference)
• NIST Chemistry Reference: N-Cyclopropylaniline(34535-98-3)
• EPA Substance Registry System: N-Cyclopropylaniline(34535-98-3)

Safety Data

• Hazardous Substances Data: 34535-98-3(Hazardous Substances Data)

Usage

General Description

N-Cyclopropylaniline, also known as cyclopropylphenylamine, is an organic chemical compound with the formula C9H11N. It is a substituted aniline with a cyclopropyl group attached to the nitrogen atom. This colorless to pale yellow liquid is primarily used in the synthesis of pharmaceuticals, agrochemicals, and other organic compounds. The cyclopropyl group in N-Cyclopropylaniline makes it a valuable building block for the synthesis of complex molecules due to its unique reactivity and steric effects. It is also used as a reagent in organic chemistry reactions, particularly in the field of medicinal and agrochemical research. Additionally, it can be used as a building block for the preparation of various functional materials and can undergo various chemical reactions to form different derivatives. Overall, N-Cyclopropylaniline is an important intermediate in organic synthesis and serves as a versatile tool for the creation of diverse chemical compounds.

Upstream product

• 108-86-1 bromobenzene 
• 765-30-0 Cyclopropylamine 
• 400777-68-6 N-benzyl-N-cyclopropyl-N-phenylamine 
• 725242-37-5 2-(cyclopropyl(phenyl)amino)acetic acid 
• 27374-25-0 [(1-Ethoxycyclopropyl)oxy]trimethylsilane 
• 62-53-3 aniline 
• 321532-64-3 N-cyclopropyl-2-phenoxyacetamide 
• 98-95-3 nitrobenzene 
• 411235-57-9 cyclopropylboronic acid 
• 98720-98-0 1-ethoxy-1-trimethylsilylcyclopropane 
• 103-70-8 Formanilid 
• 603-33-8 triphenylbismuthane 
• 16350-99-5 N-benzylformanilide 

Downstream Products

• 174180-98-4 2-Bromo-N-cyclopropyl-N-phenyl-acetamide 
• 950577-09-0 N-cyclopropyl-N-(3-iodobenzyl)aniline 
• 66223-76-5 N-phenyl hydroxy-3 propanamide 
• 103-84-4 Acetanilid 

Relevant articles and documents

Detection of Fleeting Amine Radical Cations and Elucidation of Chain Processes in Visible-Light-Mediated [3 + 2] Annulation by Online Mass Spectrometric Techniques

Visible-light-mediated photoredox reactions have recently emerged as a powerful means for organic synthesis and thus have generated significant interest from the organic chemistry community. Although the mechanisms of these reactions have been probed by a number of techniques such as NMR, fluorescence quenching, and laser flash photolysis and various degrees of success has been achieved, mechanistic ambiguity still exists (for instance, the involvement of the chain mechanism is still under debate) because of the lack of structural information about the proposed and short-lived intermediates. Herein, we present the detection of transient amine radical cations involved in the intermolecular [3 + 2] annulation reaction of N-cyclopropylaniline (CPA, 1) and styrene 2 by electrospray ionization mass spectrometry (ESI-MS) in combination with online laser irradiation of the reaction mixture. In particular, the reactive CPA radical cation 1+?, the reduced photocatalyst Ru(I)(bpz)3+, and the [3 + 2] annulation product radical cation 3+? are all successfully detected and confirmed by high-resolution MS. More importantly, the post-irradiation reaction with an additional substrate, isotope-labeled CPA, following photolysis of 1, 2, and Ru catalyst provides strong evidence to support the chain mechanism in the [3 + 2] annulation reaction. Furthermore, the key step of the proposed chain reaction, the oxidation of CPA 1 to amine radical cation 1+? by product radical cation 3+? (generated using online electrochemical oxidation of 3), is successfully established. Additionally, the coupling of ESI-MS with online laser irradiation has been successfully applied to probe the photostability of photocatalysts.

Red-Light-Induced N, N'-Dipropyl-1,13-dimethoxyquinacridinium-Catalyzed [3+2] Cycloaddition of Cyclopropylamines with Alkenes or Alkynes

A red-light-mediated [3+2] annulation of cyclopropylamines with akenes or alkynes in the presence of N,N'-dipropyl-1,13-dimethoxyquinacridinium is reported. An array of cyclopentane or cyclopentene derivatives with diverse functional groups have been obta

Novel quetiapine analogue as well as preparation method and applications thereof

The invention relates to the technical field of compounds as well as preparation methods and applications thereof, in particular to a novel quetiapine analogue as well as a preparation method and applications thereof. The compound has a structure as shown

Anti-1,2,2,3,4,4-hexamethylphosphetane 1-oxide

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