34565-32-7

Usage

Uses

Used in Plant Growth Regulation:
(±)-Pestalotin is used as a gibberellin synergist for promoting plant growth. It enhances the effects of gibberellic acid, which is a key hormone in plant growth and development, particularly in elongation processes.
Used in Agriculture:
(±)-Pestalotin is used as a plant growth stimulator in the agricultural industry to improve crop yield and quality. By working synergistically with gibberellic acid, it can potentially increase the growth rate and overall productivity of various crops.
Used in Plant Hormone Research:
(±)-Pestalotin is used as a research tool in the study of plant hormones, specifically gibberellins, to better understand their role in plant growth and development. This knowledge can be applied to develop more effective agricultural practices and improve crop management strategies.

InChI:InChI=1/C11H18O4/c1-3-4-5-9(12)10-6-8(14-2)7-11(13)15-10/h7,9-10,12H,3-6H2,1-2H3/t9-,10-/m0/s1

Upstream product

• 74590-73-1 1,3-bis(trimethylsiloxy)-1-methoxybuta-1,3-diene 
• 87678-65-7 (S)-(-)-2-benzyloxyhexanal 
• 1002-36-4 hep-2-yn-1-ol 
• 106225-85-8 methyl (S)-(+)-2-hydroxyhexanoate 
• 94286-98-3 (5S,6S)-6-(1-Ethoxy-ethoxy)-5-hydroxy-dec-2-ynoic acid 
• 94286-94-9 methyl-(5S, 6S)-6-ethoxyethoxy-5-hydroxy-2-decynoate 
• 54620-78-9 (6R, 1'RS)-6-(1'-benzyloxypentyl)-4-methoxy-5,6-dihydro-2-pyrone 
• 54620-77-8 methyl (5R, 6RS)-6-benzyloxy-5-hydroxy-2-decyonate 
• 54620-76-7 (R)-6-Benzyloxy-5-hydroxy-dec-2-ynoic acid 
• 327-57-1 L-Norleucine 
• 198635-69-7 (E)-Dec-5-en-2-ynoic acid methyl ester 
• 68703-33-3 (E)-1-chloro-2-heptene 
• 33467-76-4 (E)-hept-2-en-1-ol 
• 58930-68-0 hept-2-ynyl tetrahydropyranyl ether 

Downstream Products

• 41164-65-2 C₂₅H₃₀O₈ 

Relevant academic research and scientific papers

Divergent asymmetric total synthesis of all four pestalotin diastereomers from (R)-glycidol

All four chiral pestalotin diastereomers were synthesized in a straightforward and divergent manner from common (R)-glycidol. Catalytic asymmetric Mukaiyama aldol reactions of readily-available bis(TMSO)diene (Chan’s diene) with (S)-2-benzyloxyhexanal der

An efficient synthesis of (-)-pestalotin and its enantiomer using Sharpless asymmetric dihydroxylation

With Sharpless asymmetric dihydroxylation as a key step, syntheses of (-)-pestalotin and its enantiomer have been accomplished in a four-step sequence in high stereoselectivity.

High Diastereoselection in the Aldol Reaction of the Bistrimethylsilyl Enol Ether of Methyl Acetoacetate with 2-Benzyloxyhexanal: Synthesis of (-)-Pestalotin

Aldol condensation of the bistrimethylsilyl enol ether of methyl acetoacetate, compound 2, with 2-benzyloxyhexanal 3c affords highly selectively (99:1) the syn-aldol adduct 4c in the presence of titanium tetrachloride.The stereocontrolled synthesis of (-)-pestalotin 7 has been achieved.

Stereoselective Synthesis of 1,2-Diols by the Cycloadditive Strategy: Total Synthesis of (+/-)-exo-Brevicomin and (+/-)- and (-)-Pestalotin

Highly selective reductions of 5-acyl-2-isoxazolines and conversion of the resulting syn-5-hydroxyalkyl-2-isoxazolines into syn-diols are key steps in concise syntheses of (+/-)-exo-brevicomin, and (+/-)-pestalotin.With an asymmetric nitrile oxide as starting material, cycloaddition with the acrylate derivative of Oppolzer's camphor sultam leads to a synthesis of (-)-pestalotin.

Highly Diastereoselective Titanium Tetrachloride-mediated Aldol Condensation of the Bistrimethylsilyl Enol Ether of Acetoacetic Ester with 2-Benzyloxyhexanal. A Synthesis of (-)-Pestalotin

Titanium tetrachloride-mediated aldol condensation of the bistrimethylsilyl enol ether of methyl acetoacetate (1) with 2-benzyloxyhexanal (3) gives highly selectively (99:1) the syn aldol adduct (5); the stereocontrolled synthesis of (-)-pestalotin (9) ha