70326-39-5

Basic information

• Product Name: Hexanal, 2-(phenylmethoxy)-
• CAS NO: 70326-39-5
• Molecular Formula: C13H18O2
• Molecular Weight: 206.285
• Mol File: 70326-39-5.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Hexanal, 2-(phenylmethoxy)-(CAS DataBase Reference)
• NIST Chemistry Reference: Hexanal, 2-(phenylmethoxy)-(70326-39-5)
• EPA Substance Registry System: Hexanal, 2-(phenylmethoxy)-(70326-39-5)

Safety Data

• Hazardous Substances Data: 70326-39-5(Hazardous Substances Data)

Upstream product

• 68756-64-9 2-hydroxyhexanoic acid methyl ester 
• 70326-41-9 2-benzyloxy-hexanoyl chloride 
• 70326-42-0 2-benzyloxy-hexanoic acid 
• 110-62-3 pentanal 
• 110320-68-8 methyl 2-benzyloxyhexanoate 
• 100-39-0 benzyl bromide 
• 4938-52-7 1-hepten-3-ol 
• 119404-52-3 2-Benzyloxy-hexanoic acid benzyl ester 
• 636-36-2 rac-2-hydroxyhexanoic acid 
• 141554-36-1 2-(benzyloxy)hexan-1-ol 
• 96302-57-7 (1-Dimethoxymethyl-pentyloxymethyl)-benzene 
• 54620-75-6 (1-Vinyl-pentyloxymethyl)-benzene 
• 84994-58-1 (R)-1-((S)-2-Phenyl-hexahydro-pyrrolo[1,2-c]imidazol-3-yl)-pentan-1-ol 
• 70326-34-0 3-(2-benzyloxy-hexanoyl)-thiazolidine-2-thione 

Downstream Products

• 54620-78-9 6-<1-(Benzyloxy)hexyl>-5,6-dihydro-4-methoxy-2H-pyran-2-one 
• 66832-04-0 methyl 5-benzyloxy-6-hydroxy-8-oxodecanoate 
• 106225-84-7 2-(1'-benzyloxypentyl)-2,3-dihydro-6-methoxypyran-4-one 
• 91751-29-0 (3R,4S,5S)-5-Benzyloxy-3-methyl-non-1-en-4-ol 
• 91751-29-0 (3S,4S,5S)-5-Benzyloxy-3-methyl-non-1-en-4-ol 
• 54620-78-9 6-(1'-benzyloxypentyl)-5,6-dihydro-4-methoxypyran-2-one 
• 54620-78-9 6-(1'-benzyloxypentyl)-5,6-dihydro-4-methoxypyran-2-one 
• 99035-38-8 [(4R,5R)-5-(1-Benzyloxy-pentyl)-2,4-dimethyl-4,5-dihydro-furan-3-yl]-tert-butyl-dimethyl-silane 
• 99035-38-8 [(4R,5S)-5-(1-Benzyloxy-pentyl)-2,4-dimethyl-4,5-dihydro-furan-3-yl]-tert-butyl-dimethyl-silane 
• 99052-84-3 [(R)-5-((R)-1-Benzyloxy-pentyl)-2-methyl-4,5-dihydro-furan-3-yl]-tert-butyl-dimethyl-silane 
• 136850-73-2 6-(1'-benzyloxypentyl)-5,6-dihydropyran-2,4(3H)-dione 
• 34565-32-7 (+/-) epi-pestalotin 

Relevant articles and documents

Concentration effects in chelation controlled reactions

The diastereoselectivities of addition reactions of allyltrimethylsilane to an α-benzyloxyaldehyde were found to be relatively insensitive to the amount of added TiCl4, and to the absolute concentration of the 1:1 aldehyde/TiCl4 complex. In contrast, diastereoselectivities of similar additions to a structurally related β-benzyloxyaldehyde were highly dependent on these variables.

High Diastereoselection in the Aldol Reaction of the Bistrimethylsilyl Enol Ether of Methyl Acetoacetate with 2-Benzyloxyhexanal: Synthesis of (-)-Pestalotin

Aldol condensation of the bistrimethylsilyl enol ether of methyl acetoacetate, compound 2, with 2-benzyloxyhexanal 3c affords highly selectively (99:1) the syn-aldol adduct 4c in the presence of titanium tetrachloride.The stereocontrolled synthesis of (-)-pestalotin 7 has been achieved.

Application of Allenylsilanes in Annulation Approaches to Oxygen and Nitrogen Heterocycles

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