34586-03-3

Upstream product

• 2979-70-6 2-methyl-5-phenyl-2-pentanol 
• 33501-90-5 (4-methylpent-3-en-1-yl)benzene 
• 637-59-2 1-Bromo-3-phenylpropane 
• 1228016-21-4 C₁₆H₃₄O₄Si 
• 7484-37-9 (3-phenylpropyl)triphenylphosphonium bromide 

Downstream Products

• 28509-35-5 2-(1,1-Dimethyl-4-phenyl-butylperoxy)-ethanesulfonic acid phenyl ester 
• 79889-22-8 3,3-Dimethyl-6-phenyl-[1,2]dioxane 
• 2979-70-6 2-methyl-5-phenyl-2-pentanol 
• 69815-01-6 4-methyl-1-phenylpentane-1,4-diol 
• 135370-91-1 5-ethoxycarbonyl-4-(1,1-dimethyl-4-phenylbutylperoxy)-2-phenylpyrimidin 

Relevant academic research and scientific papers

Copper-catalyzed remote sp3 C-H chlorination of alkyl hydroperoxides

A copper-catalyzed methodology to functionalize remote sp3 C-H bonds in alkyl hydroperoxides is presented. The atom-transfer chlorination utilizes simple ammonium chloride salts as the chlorine source, and the internal redox process requires no external redox reagents.

Synthesis of cyclic peroxides by chemo- and regioselective peroxidation of dienes with Co(II)/O2/Et3SiH

(Chemical Equation Presented). In the competitive peroxidation of mixtures of two alkenes with Co(II)/O2/Et3SiH, it was found that the relative reactivities of the alkene substrates are influenced by three major factors:. (1) relative stability of the intermediate carbon-centered radical formed by the reaction of the alkene with HCo(III) complex, (2) steric effects around the C=C double bond, and (3) electronic factors associated with the C=C double bond. Consistent with results from simple alkenes, the chemo-and regioselective peroxidation of dienes was also realized. Depending on the diene structure, the product included not only the expected acyclic unsaturated triethylsilyl peroxides but also 1,2-dioxolane and 1,2-dioxane derivatives via intramolecular cyclization of the unsaturated peroxy radical intermediates.