345910-94-3

Upstream product

• 140-10-3 (E)-3-phenylacrylic acid 
• 3945-69-5 4-(4,6-dimethoxy-1,3,5-triazin-2-yl)-4-methylmorpholinium chloride 
• 3140-73-6 2-chloro-4,6-dimethoxy-1 ,3,5-triazine 

Downstream Products

• 14371-10-9 (E)-3-phenylpropenal 
• 104-53-0 3-phenyl-propionaldehyde 
• 3160-32-5 (1E)-4-methyl-1-phenylpent-1-en-3-one 

Relevant academic research and scientific papers

One-pot synthesis of cinnamic anhydrides from cinnamic acids and 6-chloro-2,4-dimethoxy-sec-triazine (CDMT) at room temperature

Symmetric cinnamic anhydrides were prepared by the reactions of cinnamic acid substrates with 6-chloro-2,4-dimethoxy-sec-triazine. The reactions were performed at room temperature for 15 h. Diverse cinnamic acid substrates bearing electron-withdrawing or -donating groups worked well, providing the corresponding cinnamic anhydrides in moderate-to-good yields.

A Simple Preparation of Ketones. N-Protected α-Amino Ketones from α-Amino Acids

matrix presented Carboxylic acids and amino acids are readily converted, under mild conditions, into the corresponding activated esters, which are reacted with Grignard/Cul reagent to give the corresponding ketones in nearly quantitative yields. The compounds were recovered substantially pure from the reaction mixtures.