3462-52-0

Basic information

• Product Name: 1-phenyl-2-(2-propen-1-yl)-4-penten-1-one
• Synonyms: 1-phenyl-2-(2-propen-1-yl)-4-penten-1-one
• CAS NO: 3462-52-0
• Molecular Weight: 200.28
• Mol File: 3462-52-0.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: 1-phenyl-2-(2-propen-1-yl)-4-penten-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: 1-phenyl-2-(2-propen-1-yl)-4-penten-1-one(3462-52-0)
• EPA Substance Registry System: 1-phenyl-2-(2-propen-1-yl)-4-penten-1-one(3462-52-0)

Safety Data

• Hazardous Substances Data: 3462-52-0(Hazardous Substances Data)

Upstream product

• 3240-29-7 1-Phenylpent-4-en-1-one 
• 106-95-6 allyl bromide 
• 98-86-2 acetophenone 
• 92954-34-2 2-allyl-1,3-dicyclohexylisourea 
• 55905-98-1 α-lithioacetophenone 
• 60-29-7 diethyl ether 
• 162707-85-9 2-(benzothiazol-2-thio)-1-phenyl-2-(2-propen-1-yl)-4-penten-1-one 
• 92954-34-2 N,N'-dicyclohexyl-O-allylisourea 
• 13735-78-9 1-phenyl-2-(trimethylsilyl)ethanone 
• 13944-95-1 2-(phenacylsulfanyl)-1,3-benzothiazole 

Downstream Products

• 129697-19-4 (5-Methoxycarbonylmethyl-6a-phenyl-hexahydro-furo[2,3-b]furan-2-yl)-acetic acid methyl ester 
• 110840-63-6 (2S,5R)-6a-phenyl-2,5-bis[(phenylseleno)methyl]hexahydrofuro[2,3-b]furan 
• 110902-54-0 (2RS,5RS)-6a-phenyl-2,5-bis[(phenylseleno)methyl]hexahydrofuro[2,3-b]furan 
• 121906-92-1 5-Allyl-4-phenyl-oct-7-en-2-yne-1,4-diol 
• 121907-05-9 5-Allyl-3-methylene-1-phenyl-2-vinyl-cyclopentanol 
• 121906-97-6 Acetic acid (E)-5-allyl-4-hydroxy-4-phenyl-octa-2,7-dienyl ester 
• 33524-58-2 cyclopent-3-en-1-yl(phenyl)methanone 
• 64207-12-1 cyclopent-2-en-1-yl(phenyl)methanone 
• 5422-88-8 phenyl cyclopentyl ketone 

Relevant articles and documents

FLUORIDE ION INDUCED REACTIONS OF ORGANOSILANES: THE PREPARATION OF MONO AND DICARBONYL COMPOUNDS FROM β-KETOSILANES.

β-ketosilanes react with a variety of carbon electrophiles in the presence of CsF to give mono- and dicarbonyl derivatives in reasonably good yields.

Platinum(IV)-Catalyzed Synthesis of Unsymmetrical Polysubstituted Benzenes via Intramolecular Cycloaromatization Reaction

A one-pot synthesis of polysubstituted benzene derivatives was achieved via a platinum(IV)-catalyzed intramolecular cycloaromatization reaction. The reaction proceeds via a tandem skeletal rearrangment, dehydration and double bond isomerization, which proved to be very useful for the syntheses of a range of interesting polyalkyl-substituted benzenes.

Reaction of tetracarbonyl(π-allyl)manganese with carbon nucleophiles

Nucleophilic attack on tetracarbony (π-allyl)manganese takes place at the terminus of the π-system, generating allylated products in 44-95% yield after oxidation. Stabilized nucleophiles (pK(a) 12-20) give mainly bis allylation whereas nonstabilized nucleophiles (pKa 25-35) give mono allylation.