34680-84-7

Basic information

• Product Name: 7-cyclohexyloxepan-2-one
• CAS NO: 34680-84-7
• Molecular Formula: C₁₂H₂₀O₂
• Molecular Weight: 196.286
• Mol File: 34680-84-7.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 309.8°C at 760 mmHg
• Flash Point: 126.8°C
• Density: 1.023g/cm³
• Vapor Pressure: 0.000627mmHg at 25°C
• Refractive Index: 1.486
• CAS DataBase Reference: 7-cyclohexyloxepan-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: 7-cyclohexyloxepan-2-one(34680-84-7)
• EPA Substance Registry System: 7-cyclohexyloxepan-2-one(34680-84-7)

Safety Data

• Hazardous Substances Data: 34680-84-7(Hazardous Substances Data)

Upstream product

• 90-42-6 d,l-2-cyclohexylcyclohexanone 
• 65181-96-6 2-(cyclohexen-1-yl)-1-cyclohexanol 
• 1502-22-3 2-(1-cyclohexenyl)cyclohexanone 
• 14660-52-7 ethyl 5-bromovalerate 
• 2043-61-0 cyclohexanecarbaldehyde 
• 2903-13-1 6-cyclohexyl-6-hydroxy-hexanoic acid 
• 854912-75-7 6-cyclohex-1-enyl-6-oxo-hexanoic acid 
• 861574-00-7 [1,1']bicyclohexyliden-2-ylamine 
• 20606-25-1 6-cyclohexyl-6-oxohexanoic acid 

Relevant articles and documents

Oxidation of the cyclopentanone and cyclohexanone alkyl derivatives in a pseudohomogeneous system without a phase transfer agent

The reaction of catalytic oxidation of C5-C12 alkyl- and cycloalkylcyclopentanones and -cyclohexanones to lactones in a pseudohomogeneous system without the participation of phase transfer agents was investigated. It was established that the catalytic systems prepared on the basis of molybdenum and tungsten blue (MeOnBrm, where Me = Mo, W, n = 1, 2, m = 2, 3) and H3PO4 deposited on powdered activated carbon AG-3 at 40-60°C, at 5-6 h duration exhibit a high selectivity in the reaction of nucleophilic addition of oxygen to the ketones with the formation of the valero- and caprolactones. Pleiades Publishing, Ltd., 2011.

MMPP (Magnesium Monoperoxyphthalate) in acetonitrile; a new approach to the synthesis of lactones via Baeyer-Villiger oxidation of cyclic ketones

A variety of unsubstituted and mono- or di-substituted cycloalkanones can be oxidised with modest excess of magnesium monoperoxyphthalate hexahydrate in acetonitrile to produce the corresponding lactones in facile, selective, and high yielding manner.