34743-25-4Relevant articles and documents
Transition metal-free α-Csp3-H oxidative sulfuration of benzyl thiosulfates with anilines to form N-aryl thioamides
Qiao, Mengjun,Zhang, Jinli,Chen, Ling,Zhou, Fengyi,Zhang, Yali,Zhou, Lingfei,Wu, Yangjie
supporting information, p. 3790 - 3796 (2019/04/17)
A metal-free approach to N-aryl thioamides from Bunte salts and anilines in DMSO has been developed. This method tolerated a wide range of functional groups on the aromatic ring, providing an ideal way to N-aryl thioamides in good to excellent yields from cheap and easily available starting materials. A plausible mechanism was also proposed based on the X-ray single crystal diffraction, NMR and MS analyses of DMSO-concerning intermediates.