347894-40-0Relevant academic research and scientific papers
High-relaxivity Gd(III)-hemicryptophane complex
Godart, Estelle,Long, Augustin,Rosas, Roselyne,Lemercier, Gilles,Jean, Marion,Leclerc, Sébastien,Bouguet-Bonnet, Sabine,Godfrin, Célia,Chapellet, Laure-Lise,Dutasta, Jean-Pierre,Martinez, Alexandre
, p. 1999 - 2003 (2019)
The polytopic hemicryptophane cage HC1 combining a cyclotriveratrylene (CTV) unit and a tris(2-aminoethyl)amine (tren) moiety connected by three 2-hydroxyisophthalamide linkers was synthesized in 12 steps. The resulting highly functionalized covalent host
Improved hemicryptophane hosts for the stereoselective recognition of glucopyranosides
Schmitt, Aline,Perraud, Olivier,Payet, Elina,Chatelet, Bastien,Bousquet, Benjamin,Valls, Marion,Padula, Daniele,Di Bari, Lorenzo,Dutasta, Jean-Pierre,Martinez, Alexandre
, p. 4211 - 4217 (2014/06/10)
Four new enantiomerically and diastereomerically pure hemicryptophane hosts (M-SSS-2/P-SSS-2 and M-RRR-2/P-RRR-2 pairs) were designed for the recognition of sugar derivatives. Their absolute configuration was determined from the circular dichroism spectra
A new class of C3-symmetrical hemicryptophane hosts: Triamide- and tren-hemicryptophanes
Raytchev, Pascal Dimitrov,Perraud, Olivier,Aronica, Christophe,Martinez, Alexandre,Dutasta, Jean-Pierre
scheme or table, p. 2099 - 2102 (2010/06/12)
Chemical Equation Presented The first hemicryptophanes derived from tris(N-alkylcarbamoylmethyl)amine and tris(2-aminoethyl)amine (tren) have been synthesized following a single synthetic pathway that allows the subsequent formation of the two heteroditopic hosts 3 and 4. X-ray crystal structures show a well-defined cavity encapsulating a solvent guest for both compounds emphasizing their complexation properties.
Synthesis of deuterium-labeled cryptophane-A and investigation of Xe@cryptophane complexation dynamics by 1D-EXSY NMR experiments
Brotin, Thierry,Devic, Thomas,Lesage, Anne,Emsley, Lyndon,Collet, Andre
, p. 1561 - 1573 (2007/10/03)
We present the synthesis of a series of deuterated cryptophanes 2-6 by a slightly modified procedure used for cryptophane-A. We show that for [Xe@cryptophane] complexes the use of variable-temperature one-dimensional 129Xe magnetization transfe
