348135-18-2

Upstream product

• 2245-30-9 1,2-epoxy-3,3-dimethylbutane 
• 87-62-7 2,6-dimethylaniline 

Downstream Products

• 349100-81-8 [((CH₃)2C₆H₃NC₂H₃(C(CH₃)3)O)Ti(N(CH₃)2)2]2 

Relevant academic research and scientific papers

Hexafluoroisopropanol as the Acid Component in the Passerini Reaction: One-Pot Access to β-Amino Alcohols

A new Passerini-type reaction in which hexafluoroisopropanol functions as the acid component is reported. The reaction tolerates a broad range of isocyanides and aldehydes, and the formed imidates can be reduced toward β-amino alcohols under mild and metal-free conditions. In addition, the imidate products were shown to undergo an unprecedented retro-Passerini-type reaction under microwave conditions, providing valuable mechanistic information about the Passerini reaction and its variations.

Synthesis of titanium(IV) complexes containing 2,6-dimethylaniline substituted amino alcohols and their utilization in ethylene polymerizations

Two new Ti(IV) complexes of the type [(OCHRCH2N-2,6-Me2Ph)Ti(NMe2)2] 2 (where R=H, or tbutyl) have been synthesized by protonolysis of Ti(NMe2)4 with the corresponding N-substituted amino alcohol ligand. The two complexes were studied as Ziegler-Natta type polymerization catalysts in the presence of an excess of methylaluminoxane (MAO). It was found that ethylene polymerization activity for both catalysts increased by increasing the polymerization temperature from 25 to 70°C. If the catalysts were pretreated with trimethylaluminum, the activities increased at 25°C, but slightly decreased at 70°C. Both complexes were found to be ineffective for the polymerization of propylene. An X-ray crystal structure of [(OCH2CH2N-2,6-Me2Ph)Ti(NMe2) 2]2 shows the complex to be dimeric in the solid state, with bridging through the amino alcohol oxygen atoms. This complex crystallizes in the monoclinic system space group, P21/n with a=9.181(6), b=13.766(3), c=13.002(3), β=93.08(3) and Z=4.