34862-82-3Relevant academic research and scientific papers
A Mechanochemical-Assisted Oxidation of Amines to Carbonyl Compounds and Nitriles
Gaspa, Silvia,Porcheddu, Andrea,Valentoni, Antonio,Garroni, Sebastiano,Enzo, Stefano,De Luca, Lidia
supporting information, p. 5519 - 5526 (2017/09/06)
A mild, efficient, metal- and solvent-free oxidation of primary amines to aldehydes, ketones, and nitriles under ball-milling conditions is presented. This method has proved to be compatible with various functional groups and only requires easily accessible starting materials. Simple purification of the reaction mixtures by short-column chromatography afforded pure aldehydes, ketones, and nitriles as products.
An insight of the reactions of amines with trichloroisocyanuric acid
De Luca, Lidia,Giacomelli, Giampaolo
, p. 2180 - 2184 (2007/10/03)
The reaction between amines or α-aminoacids with trichloroisocyanuric acid is studied under various conditions: N,N-dichloroamines, nitriles and ketones can be obtained from primary amines, while free aminoacids undergo oxidative decarboxylation to the corresponding nitrile of one less carbon atom.
