7699-76-5

Usage

Chemical compound

Benzenemethanimine, N-chloro-a-phenyl-

InChI:InChI=1/C13H10ClN/c14-15-13(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10H

Upstream product

• 1013-88-3 Benzophenone imine 
• 100-47-0 benzonitrile 
• 119-61-9 benzophenone 
• 91-00-9 Benzhydrylamine 
• 34862-82-3 N,N-Dichlor-α-phenylbenzylamin 

Downstream Products

• 78488-69-4 N-(phenyldichloroseleno)diphenylketimine 
• 82388-29-2 N-(Diphenylmethylen)methansulfenamid 
• 82388-56-5 N-(Diphenylmethylen)ethansulfenamid 
• 124842-07-5 <(diphenylmethylene)amino>triphenylphosphonium chloride 
• 93-98-1 N-phenyl benzoyl amide 
• 2866-82-2 N-(4-chlorophenyl)benzamide 
• 61294-96-0 3-phenylisoindole-1-carboxylic acid ethyl ester 
• 30081-56-2 1,3,4-triphenylisoquinoline 
• 119-61-9 benzophenone 
• 1461-22-9 tributyltin chloride 
• 82388-68-9 1,1-Diphenyl-N-thiocyanatomethanimin 
• 41987-22-8 N-(diphenylmethylene)-S-phenylthiohydroxylamine 

Relevant academic research and scientific papers

Rh(III)-catalyzed synthesis of isoquinolines using the N-Cl bond of N-chloroimines as an internal oxidant

The Rh(III)-catalyzed coupling of N-chloroimines with alkynes for the efficient synthesis of isoquinolines is reported. This represents the first use of the N-Cl bond of N-chloroimines as an internal oxidant for construction of the isoquinoline skeleton. The synthesis features atom and step economy, a green solvent (EtOH), mild reaction conditions, and a broad substrate scope.

A Mechanochemical-Assisted Oxidation of Amines to Carbonyl Compounds and Nitriles

A mild, efficient, metal- and solvent-free oxidation of primary amines to aldehydes, ketones, and nitriles under ball-milling conditions is presented. This method has proved to be compatible with various functional groups and only requires easily accessible starting materials. Simple purification of the reaction mixtures by short-column chromatography afforded pure aldehydes, ketones, and nitriles as products.

An insight of the reactions of amines with trichloroisocyanuric acid

The reaction between amines or α-aminoacids with trichloroisocyanuric acid is studied under various conditions: N,N-dichloroamines, nitriles and ketones can be obtained from primary amines, while free aminoacids undergo oxidative decarboxylation to the corresponding nitrile of one less carbon atom.

Preparations of (Alkylideneamino)sulfonium Salts, Thioxime S-Alkyl Ethers, and of (Alkylideneamino) Thiocyanates

Stable (alkylideneamino)sulfonium salts (1a - u) are obtained from α-halogen isocyanates (12) by reaction with sulfoxides (13), from the reaction of N-chloroimines (14) with sulfides (15), or by alkylation of N-alkylidenesulfenamides (16) with trimethylox