34879-53-3Relevant articles and documents
Copper-Catalyzed Oxidative Oxyamination/Diamination of Internal Alkenes of Unsaturated Oximes with Simple Amines
Liu, Rui-Hua,Wei, Dian,Han, Bing,Yu, Wei
, p. 6525 - 6530 (2016/10/18)
A convenient and versatile oxidative intra/intermolecular oxyamination and diamination of unactivated alkenes has been developed through copper-catalyzed radical reactions of β,γ- and γ,δ-unsaturated ketoximes with electron-rich aryl and aliphatic amines. These reactions were carried out by employing di-tert-butyl peroxide (DTBP) or air as the terminal oxidant, and a series of useful nitrogen-containing 4,5-dihydroisoxazoles and cyclic nitrones were formed.
An improved synthesis of isoxazolines based on Tprssell's procedure
Nagarajan, A.,Pillay, M. Krishna
, p. 471 - 474 (2007/10/02)
Isoxazolines (1-29) have been prepared in 65-75percent yield by cycloaddition of alkenes to benzonitrile oxide, 4-chlorobenzonitrile oxide and 3-nitrobenzonitrile oxide generated in situ from the respective araldoximes.A number of new isoxazolines such as