34880-68-7

Basic information

• Product Name: 2,2,6,6-tetramethyl-4-(2-phenylethylidene)-3,5-dioxa-2,6-disilaheptane
• Synonyms: 2,2,6,6-tetramethyl-4-(2-phenylethylidene)-3,5-dioxa-2,6-disilaheptane
• CAS NO: 34880-68-7
• Molecular Weight: 294.541
• Mol File: 34880-68-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2,2,6,6-tetramethyl-4-(2-phenylethylidene)-3,5-dioxa-2,6-disilaheptane(CAS DataBase Reference)
• NIST Chemistry Reference: 2,2,6,6-tetramethyl-4-(2-phenylethylidene)-3,5-dioxa-2,6-disilaheptane(34880-68-7)
• EPA Substance Registry System: 2,2,6,6-tetramethyl-4-(2-phenylethylidene)-3,5-dioxa-2,6-disilaheptane(34880-68-7)

Safety Data

• Hazardous Substances Data: 34880-68-7(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 501-52-0 3-Phenylpropionic acid 

Downstream Products

• 131683-27-7 (S)-(–)-β²-homophenylalanine 
• 26250-90-8 (3R)-benzyl-3-(tert-butoxycarbonyl)amino-propanoic acid 
• 203854-62-0 (S)-3-((((9H-fluoren-9-yl)methoxy)carbonyl)amino)-2-benzylpropanoic acid 
• 26250-90-8 (S)-2-[(tert-butoxycarbonylamino)methyl]-3-phenylpropanoic acid 
• 23052-05-3 N-phenyl-DL-phenylalanine 
• 99940-44-0 C₂₁H₃₁NO₃Si₂ 

Relevant articles and documents

The Catalytic Asymmetric Mukaiyama–Michael Reaction of Silyl Ketene Acetals with α,β-Unsaturated Methyl Esters

α,β-Unsaturated esters are readily available but challenging substrates to activate in asymmetric catalysis. We now describe an efficient, general, and highly enantioselective Mukaiyama–Michael reaction of silyl ketene acetals with α,β-unsaturated methyl esters that is catalyzed by a silylium imidodiphosphorimidate (IDPi) Lewis acid.