34896-15-6

Upstream product

• 108428-59-7 Phosphoric acid 3,5-di-tert-butyl-2-methoxy-phenyl ester dimethyl ester 
• 3383-21-9 3,5-di-tert-butyl-o-benzoquinone 
• 916675-58-6 2-(methoxy)-1-(bromomethyl)-3,5-di-tertbutylbenzene 
• 108428-51-9 4,6-Di-tert-butyl-2,2,2-trimethoxy-1,3-dioxa-2λ⁵-phospha-indan 
• 108428-58-6 1-hydroxy-3,5-di-tert-butylbenzene-2-dimethyl phosphate 
• 1020-31-1 3,5-Di-tert-butylcatechol 
• 77-78-1 dimethyl sulfate 

Relevant academic research and scientific papers

Direct oxidation of the C(sp2)-C(sp3) bond from benzyltrimethylsilanes to phenols

A novel pathway for direct conversion of benzylsilanes to phenols by oxidation with Na2S2O8 and oxygen is efficiently developed under mild and neutral conditions. The reaction shows good functional group tolerance to afford phenols in moderate yields. The possible mechanism is proposed based on the isotopic labeling trials.

O-Methylation of tert-Alkylpyrocatecholes. Analytical Method for Determination of the Content of Product Mixtures and Way for Preparation of 4-tert-Alkylveratroles

The O-methylation of tert-alkylpyrocatecholes with dimethylsulfate leads to a mixture of substituted guaiacoles 6/7, 9/10 and veratroles 5, 6 which are separated by gas/liquid-chromatography for analytical purposes.It is also possible to prepare 4-tert-alkylsubstituted veratroles 5 with good yields in this way.On the other hand, the alkylation of veratrole was only successful with lower tert-alkanols or alkenes.Long-chained tert-alkanols fail in this reaction.The analytical and spectroscopical data of some new 4-tert-alkylveratroles 5a-g are given.

THE REACTION OF ALKYL PHOSPHITES WITH 3,5-DI-TERT-BUTYL-1,2-BENZOQUINONE. VARIABLE TEMPERATURE NMR STUDIES ON NEW PENTAOXYPHOSPHORANES

3,5-Di-tert-butyl-1,2-benzoquinone (5) reacts with trialkyl phosphites (6) to give the respective pentaoxyphosphoranes 7.On the other hand, the reaction of quinone 5 with dialkyl phosphites affords the phosphonate adducts 13.Analytical and spectroscopic (