34938-46-0Relevant articles and documents
Gold(I) phosphine complexes containing selenocarbamate esters: Crystal and molecular structure of N-phenyl-O-methylselenocarbamate
Gallenkamp, Daniel,Tiekink, Edward R. T.,Mohr, Fabian
, p. 1050 - 1056 (2008)
A series of both mono- and dinuclear gold(I) phosphine complexes containing deprotonated N-phenyl-O-methylselenocarbamate of the type [AuSeC(OMe) = NPh(P)] and [Au2SeC(OMe) = NPh2(PP)] (P = PPh3, P(o-tolyl)3, PTA; PP = dppm, dppe, dppp, dppf) were prepared and characterized by spectroscopic techniques. The X-ray crystal structure of SeC(OMe)=N(H)Ph is also reported and shows the molecule to exist in the E-conformation. Centrosymmetrically related dimers associate in the crystal structure by N-H...Se interactions.