349544-22-5Relevant academic research and scientific papers
Intramolecular amidomercurations under allylic control: A stereoselective synthesis of (+)-pseudohygroline and (+)-3-hydroxypyrrolizidine
Enierga, Gina,Espiritu, Maria,Perlmutter, Patrick,Pham, Ngoc,Rose, Mark,Sjoeberg, Stefan,Thienthong, Neeranat,Wong, Katie
, p. 597 - 604 (2001)
The diastereoselectivity of intramolecular amidomercurations can be reversed by altering the remote allylic substituent of ω-alkenylcarbamates. This methodology has been applied to the synthesis of (+)-pseudohygroline and (+)-3-hydroxypyrrolizidine.
