349583-90-0

Upstream product

• 349583-75-1 (2R,4R,5R,6R',3S')-2-benzyloxymethyl-2-methyl-4-dimethylphenylsilanyl-5-[6'-triethylsilanyloxy-3'-benzyloxy-3'-methyl-1'-tert-butyldimethylsilanyloxy-hex-6'-yl]-tetrahydrofuran 
• 349583-71-7 (2R,4R,5R,6R',3S')-[5-(6'-triethylsilanyloxy-3'-benzyloxy-3'-methyl-1'-tert-butyldimethylsilanyloxy-hex-6'-yl)-4-dimethylphenylsilanyl-2-methyltetrahydrofuran-2-yl]-formic acid methyl ester 
• 349583-84-2 (2R,4R,5R,6'R,3'S)-2-hydroxymethyl-2-methyl-4-dimethylphenylsilanyl-5-[6'-triethylsilanyloxy-3'-benzyloxy-3'-methyl-1'-tert-butyldimethylsilanyloxy-hex-6'-yl]-tetrahydrofuran 
• 349583-78-4 (2R,5R,4'S,6'R,7'S)-2-benzyloxymethyl-2-methyl-5-[4'-benzyloxy-4'-methyl-6'-hydroxy-7'-dimethylphenylsilanyl-8'-ene-1'-one-1'-yl]-tetrahydrofuran 
• 349583-69-3 (3S,6R,7S)-1-tert-butyldimethylsilanyloxy-3-benzyloxy-3-methyl-6-triethylsilanyloxy-7-dimethylphenylsilanyl-non-8-ene 
• 349583-77-3 (S)-3-Benzyloxy-6-((2R,5R)-5-benzyloxymethyl-5-methyl-tetrahydro-furan-2-yl)-3-methyl-6-oxo-hexanal 
• 349583-67-1 (3-benzyloxy-3,7-dimethyl-oct-6-enyloxy)-tert-butyl-dimethyl-silane 
• 327628-39-7 4-benzyloxy-6-(tert-butyl-dimethyl-silanyloxy)-4-methyl-hexanal 
• 100-39-0 benzyl bromide 
• 349583-80-8 (4S,6R,2'R,5'R,2''R,4''R,5''R)-1-[2'-methyl-2'-benzyloxymethyl-tetrahydrofuran-5'-yl]-6-[2''-methyl-2''-carbomethoxy-4''-dimethylphenylsilanyl-tetrahydrofuran-5''-yl]-4-benzyloxy-4-methyl-6-triethylsilanyloxy-hex-1-one 
• 349583-88-6 (2R,5R,4'S,6'R,7'S)-2-benzyloxymethyl-2-methyl-5-[4'-benzyloxy-4'-methyl-6'-triethylsilanyloxy-7'-dimethylphenylsilanyl-8'-ene-1'-one-1'-yl]-tetrahydrofuran 
• 123748-58-3 (3S)-3,7-dimethyl-oct-6-ene-1,3-diol 
• 82188-73-6 (2S,3S)-2,3-epoxygeraniol 
• 349583-86-4 (2R,5R,6'R,3'S)-2-benzyloxymethyl-2-methyl-5-[1',6'-dihydroxy-3'-benzyloxy-3'-methyl-6'-hex-6'-yl]-tetrahydrofuran 

Relevant academic research and scientific papers

Studies on the synthesis of pectenotoxin II: Synthesis of a C(11)-C(26) fragment precursor via [3 + 2]-annulation reactions of chiral allylsilanes

(formula presented) A synthesis of tetracycle 2 corresponding to the C(11)-C(26) fragment of pectenotoxin II is described. The synthesis features two highly stereoselective [3 + 2]-annulation reactions of chiral allylsilanes, generated via allylboration o