349648-25-5

Upstream product

• 100-39-0 benzyl bromide 
• 349648-19-7 (R)-3-((S)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-pent-1-en-4-yn-3-ol 
• 349648-21-1 3-((S)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-1,5-bis-trimethylsilanyl-penta-1,4-diyn-3-ol 
• 60456-21-5 methyl (4S)-2,2-dimethyl-1,3-dioxolane-4-carboxylate 
• 349648-22-2 3-((S)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-penta-1,4-diyn-3-ol 

Downstream Products

• 349648-26-6 (S)-4-((R)-1-Benzyloxy-1-vinyl-dec-2-ynyl)-2,2-dimethyl-[1,3]dioxolane 
• 349648-27-7 (R)-2-Benzyloxy-2-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-undec-3-ynal 

Relevant academic research and scientific papers

Pseudo-C3-Symmetric Tertiary Alcohol Building Block via Group-Selective Hydroalumination: A Synthesis of (-)-Malyngolide

(matrix presented) The stereocontrolled preparation of tertiary alcohol 4 and its TMS surrogate 5, which share a pseudo-C3-symmetry, is described. Compound 4 was used for the synthesis of (-)-malyngolide.