34971-28-3Relevant articles and documents
Synthesis of 3-diaminomethylene-2(3H)-furanones by reaction of 2-amino-4,5-dihydro-3-furancarboxamides with amines
Yamagata, Kenji,Okabe, Fumi,Yamazaki, Motoyoshi,Tagawa, Yoshinobu
, p. 643 - 651 (2007/10/03)
The reaction of 2-amino-4,5-dihydro-3-furancarboxamides with morpholine in the presence of acetic acid in pyridine or under the influence of ammonium acetate gave the corresponding 3-diaminomethylene-4,5-dihydro-2(3H)-furanones; 4,5-dihydro-2-morpholino-3-furancarboxamides were not isolated. One of the former reacted with benzylamine to give (E)- and (Z)-3-(amino-(benzylamino)-methylene)-4,5-dihydro-4-phenyl-2(3H)-furanones and 2-benzylamino-4,5-dihydro-4-phenyl-3-furancarboxamide.