34980-76-2Relevant academic research and scientific papers
[bmim]OH-promoted one-pot, three-component synthesis of β-nitro sulfides in water
Movassagh, Barahman
, p. 1114 - 1117 (2016/07/27)
A task-specific ionic liquid, [bmim]OH, has been found to be a highly efficient catalyst for one-pot, three-component coupling of aryl aldehydes, nitromethane, and thiols for the synthesis of β-nitro sulfides in water. The main advantages of the present p
An expeditious, highly efficient, catalyst-free and solvent-free synthesis of nitroamines and nitrosulfides by Michael addition
Choudhary, Garima,Peddinti, Rama Krishna
, p. 276 - 282 (2011/04/17)
A simple, atom economical, fast and highly efficient green protocol has been developed for the synthesis of nitroamines and nitrosulfides by the Michael addition of amines and thiols to nitroolefins by simple mixing or grinding. This catalyst-free and solvent-free green approach provided the addition products in quantitative yield within minutes at room temperature. This procedure does not require any water quenches, solvent separations and purification steps such as recrystallization and column chromatography.
Straightforward and highly efficient catalyst-free regioselective reaction of thiol to β-nitrostyrene: a concise synthesis of vinyl sulfide and nitro sulfide
Chu, Cheng-Ming,Tu, Zhijay,Wu, Pohsi,Wang, Chieh-Chieh,Liu, Ju-Tsung,Kuo, Chun-Wei,Shin, Yu-Hsuan,Yao, Ching-Fa
scheme or table, p. 3878 - 3885 (2009/09/30)
Under catalyst-free reaction conditions, solvent-mediated addition of thiol 2 to β-nitrostyrene 1 proceeded with regioselective control to afford either adduct 3 or vinyl sulfide 4 in good to excellent yield. Thermodynamic and autocatalytic reaction mecha
Green procedure for the synthesis of β-nitro sulfides by Michael addition of thiols to nitroolefins
Hui, Xin-Ping,Yin, Chao,Ma, Jun,Xu, Peng-Fei
experimental part, p. 676 - 690 (2009/07/18)
Michael addition of thiols to nitroolefins was carried out in water at room temperature without any catalyst, and β-nitro sulfides were obtained in excellent yields. This is the first example of Michael addition of thiols to nitroolefins in water without
