350009-79-9Relevant academic research and scientific papers
Thwarting β-hydride elimination: Capture of the alkylpalladium intermediate of an asymmetric intramolecular heck reaction
Oestreich, Martin,Dennison, Philip R.,Kodanko, Jeremy J.,Overman, Larry E.
, p. 1439 - 1442 (2001)
In spite of containing three conformationally accessible β-H atoms, palladacycle 1a is an isolable intermediate in the asymmetric Heck cyclization of 2a. Although 1a is stable in the presence of the hydrotriflate salt of 1,2,2,6,6-pentamethylpiperidine, i
