350036-79-2

Upstream product

• 350036-76-9 methyl 4-methyl-4-nitro-5-phenyl-5-(diphenyl-phosphoryloxy)pentanoate 
• 350036-74-7 1-phenyl-1-(2-tetrahydropyranoxy)-2-nitropropanol 
• 574754-48-6 5-hydroxy-4-methyl-4-nitro-5-phenyl-pentanoic acid methyl ester 
• 350036-75-8 methyl 4-methyl-4-nitro-5-phenyl-5-(2-tetrahydropyranoxy)pentanoate 
• 100-52-7 benzaldehyde 
• 2524-64-3 chlorophosphoric acid diphenyl ester 
• 26251-08-1 2-nitro-1-phenylpropan-1-ol 

Downstream Products

• 129055-67-0 5-benzyl-5-methyl-2-tetrahydrofuranone 

Relevant academic research and scientific papers

Tandem polar/radical crossover sequences for the formation of fused and bridged bicyclic nitrogen heterocycles involving radical ionic chain reactions, and alkene radical cation intermediates, performed under reducing conditions: Scope and limitations

It is demonstrated that phosphorylated forms of β-nitro alcohols provide an excellent means of entry into β-(phosphatoxy)alkyl radicals on exposure to tributyltin hydride and AIBN in benzene at reflux. These radicals then undergo heterolytic cleavage of t

Generation and reaction of alkene radical cations under nonoxidizing conditions: Synthesis of the pyrrolizidine nucleus

(equation presented) Stable β-phosphatoxy nitroalkanes, readily assembled by the Henry reaction and subsequent phosphorylation, serve as good precursors to alkene radical cations on treatment with triphenyltin or tributyl hydride and AIBN in benzene at re