350048-97-4

Upstream product

• 127-65-1 chloroamine-T 
• 350049-02-4 10-phenylseleno-p-mentha-1,8-diene 
• 161115-51-1 (S)-1-(chloromethyl)-4-(prop-1-en-2-yl)cyclohex-1-ene 

Relevant academic research and scientific papers

Synthesis and reactions of organic compounds with a nitrogen atom. Part XVII. Reactions of acyclic and monocyclic chlorides with phenyltelluro- and phenylselenosodium

The reaction of neryl (3), geranyl (4), (+)-carvotanacetyl (5), (-)-carvyl (6) and perillyl (7) chlorides with phenylseleno-(1) or phenyltellurosodium (2), and then with chloramine-T afforded α,β-unsaturated toluenesulfonamides 8-11, which were reduced with sodium in liquid ammonia to allylic amines 12-15. Allylic phenyltellurides were oxidized by air to carbonyl compounds 29-31 or alcohol 28.