35034-15-2

Usage

InChI:InChI=1/C4H5N3O/c5-4-6-2-1-3-7(4)8/h1-3,5,8H/b5-4+

Upstream product

• 109-12-6 2-aminopyrimidine 
• 1722-12-9 2-chloropyrimidine 

Downstream Products

• 123488-66-4 2-(4-Chloro-phenyl)-imidazo[1,2-a]pyrimidin-3-ol 
• 102361-84-2 2-(2,4-dimethoxyphenyl)-3-hydroxyimidazo<1,2-a>pyrimidine 
• 109-12-6 2-aminopyrimidine 
• 5428-89-7 5-chloropyrimidin-2-amine 
• 88089-61-6 5-chloro-2-aminopyrimidine 1-oxide 
• 7752-82-1 5-bromo-2-aminopyrimidine 
• 84539-23-1 5-bromo-2-aminopyrimidine 1-oxide 
• 90998-01-9 5-hydroxy-2-pyrimidinediazotic acid 
• 80830-63-3 N,N'-Bis-(1-oxy-pyrimidin-2-yl)-C-phenyl-methanediamine 

Relevant academic research and scientific papers

AN IMPROVED PROCEDURE FOR THE PREPARATION OF AROMATIC HETEROCYCLIC N-OXIDES

An improved procedure for the preparation of aromatic heterocyclic N-oxide is described.Nitrogen containing heterocyclic compounds gave their N-oxides in excellent yields by the reaction of m-CPBA in DMF/MeOH in the presence of HF in a short time under mild reaction conditions.The presence of HF and MeOH is crucial for the reaction.

Synthesis and antifungal activity evaluation of 3-hydroxyimidazo[1,2-a]pyridine and 3-hydroxyimidazo[1,2-a]pyrimidine derivatives

A series of 16 imidazo[1,2-a]pyridine and imidazo[1,2-a]pyrimidine derivatives was synthesized and tested on several species for 'in vitro' fungicide activity.

Synthesis of some pyrimidine N-oxides

Various monosubstitudes pyrimidines and methylpyrimidines were N-oxidized with a number of different peracids.In general, they are more susceptible to side reactions accompanying N-oxidation (i.e., decomposition, annular carbon oxidation, ring opening) than other ?-deficient diazine and triazine analogs.Unsymmetrical pyrimidines, which can potentially yield two isomeric products, were N-oxidized preferentially at the site para to strong electron-donating substituents.Weaker ringactivating groups, such as methyl, are mainly ortho directing and only aid in the N-oxidation of pyrimidine nuclei having ortho/para-directing substituents.

SYNTHESES AND TRANSFORMATIONS OF SOME HETEROCYCLIC HYDROXYLAMINES

Syntheses of some hydroxylaminoazines, their quaternized derivatives or N-oxides and N-amino compounds are described.Several transformations of these compounds and cyclization reactions are presented.