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METRIBUZIN-DESAMINO, also known as Desaminometribuzin, is a derivative of Metribuzin (M338920), which is an aminotriazinone herbicide. It is primarily used in the agricultural industry for controlling the growth of unwanted plants. METRIBUZIN-DESAMINO works by inhibiting photosynthesis, specifically by disrupting photosystem II, which is a crucial component of the photosynthetic process in plants.

35045-02-4

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35045-02-4 Usage

Uses

Used in Agricultural Industry:
METRIBUZIN-DESAMINO is used as a herbicide for preand post-emergence control of weeds in various crops. It is particularly effective in soybean, potatoes, tomatoes, and sugar cane cultivation. The application of METRIBUZIN-DESAMINO helps to reduce the competition between weeds and the desired crops, ensuring better growth and yield.
Application Reason:
The primary reason for using METRIBUZIN-DESAMINO in agriculture is its ability to inhibit photosynthesis in unwanted plants, thereby controlling their growth and allowing the desired crops to thrive. By disrupting photosystem II, METRIBUZIN-DESAMINO effectively suppresses the energy production in weeds, leading to their eventual death and providing a competitive advantage to the cultivated crops.

Check Digit Verification of cas no

The CAS Registry Mumber 35045-02-4 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,5,0,4 and 5 respectively; the second part has 2 digits, 0 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 35045-02:
(7*3)+(6*5)+(5*0)+(4*4)+(3*5)+(2*0)+(1*2)=84
84 % 10 = 4
So 35045-02-4 is a valid CAS Registry Number.
InChI:InChI=1/C8H13N3OS/c1-8(2,3)5-6(12)9-7(13-4)11-10-5/h1-4H3,(H,9,11,12)

35045-02-4SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 20, 2017

Revision Date: Aug 20, 2017

1.Identification

1.1 GHS Product identifier

Product name 6-tert-butyl-3-methylsulfanyl-2H-1,2,4-triazin-5-one

1.2 Other means of identification

Product number -
Other names DEAMINOMETRIBUZIN

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:35045-02-4 SDS

35045-02-4Relevant academic research and scientific papers

SPECIFIC DEAMINATION OF 4-AMINO-1,2,4-TRIAZIN-5(4H)-ONES BY CATALYTIC OXIDATION WITH t-BUTYLHYDROPEROXIDE. A CHEMICAL MODEL FOR METABOLISM OF 1,2,4-TRIAZINE HERBICIDES

Nakayama, Y.,Sanemitsu, Y.,Yoshioka, H.,Nishinaga, A.

, p. 2499 - 2500 (1982)

The oxidation of 4-amino-1,2,4-triazine herbicides (1) with t-butylhydroperoxide catalyzed by Co(Salen) resulted in the specific deamination of the 4-amino group, providing a chemical model for the metabolism of the herbicides.

Photocatalytic mitigation of triazinone herbicide residues using titanium dioxide in slurry photoreactor

Vela,Fenoll,Garrido,Navarro,Gambín,Navarro

, p. 70 - 77 (2015)

Heterogeneous photocatalysis offers an alternative for the treatment of wastewater containing refractory pollutants. The photocatalytic degradation of metamitron and metribuzin, asymmetrical triazine compounds used worldwide as herbicides, was investigate

Biomimetic oxidation of metribuzin with hydrogen peroxide catalyzed by 5,10,15,20-tetraarylporphyrinatoiron(III) chlorides

Chauhan, Shive M.S.,Kumari, Pratibha

, p. 5035 - 5038 (2008/02/12)

The biomimetic oxidation of metribuzin, a pre- and post-emergence herbicide with hydrogen peroxide catalyzed by 5,10,15,20-tetraarylporphyrinatoiron(III) chlorides [TAPFe(III)Cl], has been studied yielding 6-t-butyl-3-methylthio-1,2,4-triazine-5(4H)-one, 4-amino-6-t-butyl-3,5(2H,4H)-dione and 6-t-butyl-1,2,4-triazin-3,5(2H,4H)-dione under various reaction conditions.

A Contribution to the Photoinduced Desamination of 1,2,4-Triazinones

Herrmann, M.,Parlar, H.,Korte, F.

, p. 117 - 118 (2007/10/02)

Solution-phase photoreactions of 4-amino-substituted 1,2,4-triazin-5(4H)-ones (1a-j) in different solvents using UV light with wavelengths greater than 290 nm have been investigated.The results show, that the desamination reaction is influenced by both oxygen and water.The photoexperiments showed clearly that OOH-radicals take part in the first step of reaction. - Key words: Photochemical Reactivity, Desamination, 1,2,4-Triazin-5(4H)-ones

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