350715-45-6

Basic information

• Product Name: (1S,2R,4S,5S,9R,11S,12S)-5-(tert-Butyl-dimethyl-silanyloxy)-11,12-dihydroxy-2-(4-methoxy-benzyloxy)-4,15,15-trimethyl-8-methylene-tricyclo[10.2.1.0^4,9]pentadecan-3-one
• Synonyms: (1S,2R,4S,5S,9R,11S,12S)-5-(tert-Butyl-dimethyl-silanyloxy)-11,12-dihydroxy-2-(4-methoxy-benzyloxy)-4,15,15-trimethyl-8-methylene-tricyclo[10.2.1.0^4,9]pentadecan-3-one
• CAS NO: 350715-45-6
• Molecular Weight: 572.858
• Mol File: 350715-45-6.mol

Chemical Properties

• CAS DataBase Reference: (1S,2R,4S,5S,9R,11S,12S)-5-(tert-Butyl-dimethyl-silanyloxy)-11,12-dihydroxy-2-(4-methoxy-benzyloxy)-4,15,15-trimethyl-8-methylene-tricyclo[10.2.1.0^4,9]pentadecan-3-one(CAS DataBase Reference)
• NIST Chemistry Reference: (1S,2R,4S,5S,9R,11S,12S)-5-(tert-Butyl-dimethyl-silanyloxy)-11,12-dihydroxy-2-(4-methoxy-benzyloxy)-4,15,15-trimethyl-8-methylene-tricyclo[10.2.1.0^4,9]pentadecan-3-one(350715-45-6)
• EPA Substance Registry System: (1S,2R,4S,5S,9R,11S,12S)-5-(tert-Butyl-dimethyl-silanyloxy)-11,12-dihydroxy-2-(4-methoxy-benzyloxy)-4,15,15-trimethyl-8-methylene-tricyclo[10.2.1.0^4,9]pentadecan-3-one(350715-45-6)

Safety Data

• Hazardous Substances Data: 350715-45-6(Hazardous Substances Data)

Upstream product

• 350715-38-7 (1S,2R,4S,5S,9R,11S,12S)-5,11,12-Trihydroxy-2-(4-methoxy-benzyloxy)-4,15,15-trimethyl-8-methylene-tricyclo[10.2.1.0^4,9]pentadecan-3-one 
• 350715-39-8 (1S,4R,8S,9S,10R,11R,12S)-1,8,10-Trihydroxy-11-(4-methoxy-benzyloxy)-9,15,15-trimethyl-5-methylene-tricyclo[10.2.1.0^4,9]pentadecan-2-one 
• 350715-36-5 4-[(1S,5S,7S,8R,10R,11S)-10-(4-Methoxy-benzyloxy)-8,14,14-trimethyl-3,9-dioxo-2,4-dioxa-tricyclo[9.2.1.0^1,5]tetradec-7-yl]-pent-4-enal 
• 350715-47-8 (1S,4R,8S,9R,10R,11R,12S)-8-(tert-Butyl-dimethyl-silanyloxy)-1,10-dihydroxy-11-(4-methoxy-benzyloxy)-9,15,15-trimethyl-5-methylene-tricyclo[10.2.1.0^4,9]pentadecan-2-one 

Downstream Products

• 512828-46-5 C₄₀H₅₄O₉Si 
• 512780-87-9 C₄₀H₅₄O₉Si 
• 512828-44-3 C₄₀H₅₆O₈Si 
• 512828-43-2 (E)-(1S,2R,4S,5S,9R,12S)-11-Benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-12-hydroxy-2-(4-methoxy-benzyloxy)-4,15,15-trimethyl-8-methylene-tricyclo[10.2.1.0^4,9]pentadec-10-en-3-one 
• 512828-45-4 C₃₃H₅₀O₈Si 
• 512828-35-2 (1S,3S,4R,8S,9S,11R,12S)-8-(tert-Butyl-dimethyl-silanyloxy)-1,3-dihydroxy-11-(4-methoxy-benzyloxy)-9,15,15-trimethyl-5-methylene-tricyclo[10.2.1.0^4,9]pentadecane-2,10-dione 
• 512783-21-0 C₃₃H₅₀O₆Si 
• 832724-37-5 (Z)-(1S,2R,4S,5S,9R,12R)-5-(tert-Butyl-dimethyl-silanyloxy)-12-hydroxy-2-(4-methoxy-benzyloxy)-4,15,15-trimethyl-8-methylene-tricyclo[10.2.1.0^4,9]pentadec-10-en-3-one 
• 832724-36-4 Methanesulfonic acid (1S,2S,4R,8S,9S,11R,12S)-8-(tert-butyl-dimethyl-silanyloxy)-1-hydroxy-11-(4-methoxy-benzyloxy)-9,15,15-trimethyl-5-methylene-10-oxo-tricyclo[10.2.1.0^4,9]pentadec-2-yl ester 
• 512828-34-1 (1S,4R,8S,9S,11R,12S)-8-(tert-Butyl-dimethyl-silanyloxy)-1-hydroxy-11-(4-methoxy-benzyloxy)-9,15,15-trimethyl-5-methylene-tricyclo[10.2.1.0^4,9]pentadecane-2,10-dione 

Relevant articles and documents

Stereospecific anionically promoted transannular hydride shifts in medium-ring hydroxy ketones. Probe of their reversibility and the potential for regiocontrol.

Examples are provided of stereospecific transannular oxidation-reduction processes involving the conjugate bases of delta-hydroxy ketones in a nine-membered ring setting. The ability to control the direction of these equilibria by proper modulation of the