512780-87-9

Upstream product

• 512828-46-5 C₄₀H₅₄O₉Si 
• 512828-44-3 C₄₀H₅₆O₈Si 
• 512828-43-2 (E)-(1S,2R,4S,5S,9R,12S)-11-Benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-12-hydroxy-2-(4-methoxy-benzyloxy)-4,15,15-trimethyl-8-methylene-tricyclo[10.2.1.0^4,9]pentadec-10-en-3-one 
• 512828-34-1 (1S,4R,8S,9S,11R,12S)-8-(tert-Butyl-dimethyl-silanyloxy)-1-hydroxy-11-(4-methoxy-benzyloxy)-9,15,15-trimethyl-5-methylene-tricyclo[10.2.1.0^4,9]pentadecane-2,10-dione 
• 350715-45-6 (1S,2R,4S,5S,9R,11S,12S)-5-(tert-Butyl-dimethyl-silanyloxy)-11,12-dihydroxy-2-(4-methoxy-benzyloxy)-4,15,15-trimethyl-8-methylene-tricyclo[10.2.1.0^4,9]pentadecan-3-one 
• 98-88-4 benzoyl chloride 
• 512828-45-4 C₃₃H₅₀O₈Si 

Downstream Products

• 512780-89-1 Benzoic acid (1S,2S,3R,7S,8S,10R,11S)-7-(tert-butyl-dimethyl-silanyloxy)-1-hydroxy-4-hydroxymethyl-10-(4-methoxy-benzyloxy)-8,15,15-trimethyl-9,14-dioxo-tricyclo[9.3.1.0^3,8]pentadec-4-en-2-yl ester 
• 512780-97-1 Benzoic acid (1S,2S,3R,5S,7S,8S,10R,11S)-7-(tert-butyl-dimethyl-silanyloxy)-1,5-dihydroxy-10-(4-methoxy-benzyloxy)-8,15,15-trimethyl-4-methylene-9,14-dioxo-tricyclo[9.3.1.0^3,8]pentadec-2-yl ester 
• 512780-95-9 C₄₀H₅₄O₁₀Si 
• 512781-00-9 Benzoic acid (1S,2S,3R,4S,5S,7S,8S,10R,11S)-7-(tert-butyl-dimethyl-silanyloxy)-1,4,5-trihydroxy-4-hydroxymethyl-10-(4-methoxy-benzyloxy)-8,15,15-trimethyl-9,14-dioxo-tricyclo[9.3.1.0^3,8]pentadec-2-yl ester 
• 512781-05-4 Benzoic acid (1S,2S,3R,4S,5S,7S,8S,10R,11S)-7-(tert-butyl-dimethyl-silanyloxy)-1,4-dihydroxy-4-hydroxymethyl-5-methanesulfonyloxy-10-(4-methoxy-benzyloxy)-8,15,15-trimethyl-9,14-dioxo-tricyclo[9.3.1.0^3,8]pentadec-2-yl ester 
• 512781-02-1 Benzoic acid (1S,2S,3R,4S,5S,7S,8S,10R,11S)-7-(tert-butyl-dimethyl-silanyloxy)-1,4,5-trihydroxy-10-(4-methoxy-benzyloxy)-8,15,15-trimethyl-9,14-dioxo-4-trimethylsilanyloxymethyl-tricyclo[9.3.1.0^3,8]pentadec-2-yl ester 
• 512781-04-3 Benzoic acid (1S,2S,3R,4S,5S,7S,8S,10R,11S)-7-(tert-butyl-dimethyl-silanyloxy)-1,4-dihydroxy-5-methanesulfonyloxy-10-(4-methoxy-benzyloxy)-8,15,15-trimethyl-9,14-dioxo-4-trimethylsilanyloxymethyl-tricyclo[9.3.1.0^3,8]pentadec-2-yl ester 
• 913182-21-5 C₄₉H₆₀O₁₀SeSi 
• 913182-20-4 C₄₆H₅₆O₁₀SeSi 

Relevant academic research and scientific papers

A delicate balance of energetics. Subtleties associated with α-ketol-based bridge migration to afford 9-keto-10β-p-methoxybenzyloxytaxanes

The feasibility of the title reaction has been pursued for the purpose of advancing a concise total synthesis of Taxol. Of the two closely related series examined, the first featured an exo-methylene group at C4. The second consisted of an α-epoxide at th