350798-25-3

Basic information

• Product Name: formic acid-(N,N'-dimethyl-N'-phenyl-hydrazide)
• Synonyms: formic acid-(N,N'-dimethyl-N'-phenyl-hydrazide)
• CAS NO: 350798-25-3
• Molecular Weight: 164.207
• Mol File: 350798-25-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: formic acid-(N,N'-dimethyl-N'-phenyl-hydrazide)(CAS DataBase Reference)
• NIST Chemistry Reference: formic acid-(N,N'-dimethyl-N'-phenyl-hydrazide)(350798-25-3)
• EPA Substance Registry System: formic acid-(N,N'-dimethyl-N'-phenyl-hydrazide)(350798-25-3)

Safety Data

• Hazardous Substances Data: 350798-25-3(Hazardous Substances Data)

Upstream product

• 10535-67-8 trimethylacetic formic anhydride 
• 29195-01-5 N'-methyl-N-methyl-N-phenylhydrazine 
• 618-40-6 1-Methyl-1-phenylhydrazine 
• 74147-38-9 1,1-Methylphenyl-2-methyl-3,3-dimethyl-formamidrazoniumiodid 
• 38604-67-0 N'-methyl-N'-phenylformohydrazide 

Downstream Products

• 76579-56-1 N,N,N'-trimethyl-N'-phenylhydrazine 
• 1170697-26-3 benzoic acid N,N'-dimethyl-N'-phenylhydrazide 
• 29195-01-5 N'-methyl-N-methyl-N-phenylhydrazine 

Relevant articles and documents

Synthesis of indoles via alkylidenation of acyl hydrazides

Indoles have been synthesised via alkylidenation of acyl phenylhydrazides using phosphoranes and the Petasis reagent, followed by in situ thermal rearrangement of the product enehydrazines. The Petasis reagent provides an essentially neutral equivalent of the [acid-catalysed] Fischer indole synthesis, but with acyl phenylhydrazides as starting substrates. Alkylidene triphenylphosphoranes convert aroyl phenylhydrazides to indoles, but acyl phenylhydrazides derived from aliphatic carboxylic acids undergo a Brunner reaction to form indolin-2-ones.