351025-66-6

Basic information

• Product Name: (4-t-BuC₆H₄NCH₂CH₂)3NMo-⁽¹⁵⁾N=⁽¹⁵⁾N-Me
• CAS NO: 351025-66-6
• Molecular Weight: 680.803
• Mol File: 351025-66-6.mol

Chemical Properties

• CAS DataBase Reference: (4-t-BuC₆H₄NCH₂CH₂)3NMo-⁽¹⁵⁾N=⁽¹⁵⁾N-Me(CAS DataBase Reference)
• NIST Chemistry Reference: (4-t-BuC₆H₄NCH₂CH₂)3NMo-⁽¹⁵⁾N=⁽¹⁵⁾N-Me(351025-66-6)
• EPA Substance Registry System: (4-t-BuC₆H₄NCH₂CH₂)3NMo-⁽¹⁵⁾N=⁽¹⁵⁾N-Me(351025-66-6)

Safety Data

• Hazardous Substances Data: 351025-66-6(Hazardous Substances Data)

Upstream product

• 80-48-8 methyl p-toluene sulfonate 

Downstream Products

• 351025-81-5 (((4-t-BuC₆H₄NCH₂CH₂)3N)Mo=N-N(⁽¹³⁾CH₃)(CH₃))OTf 
• 351025-78-0 (((4-t-BuC₆H₄NCH₂CH₂)3N)Mo=N-NMe₂)OTf 
• 351025-84-8 (((4-t-BuC₆H₄NCH₂CH₂)3N)Mo=⁽¹⁵⁾N-⁽¹⁵⁾NMe₂)OTf 

Relevant articles and documents

Synthesis, structure, and electrochemical studies of molybdenum and tungsten dinitrogen, diazenido, and hydrazido complexes that contain aryl-substituted triamidoamine ligands

One-electron reduction of [ArN3N]MoCl complexes (Ar = C6H5, 4-FC6H4, 4-t-BuC6H4, 3,5-Me2C6H3) yields complexes of the type [ArNr3N]Mo-N=N-Mo[ArN3N], while two-electron reduction yields {[ArN3N]Mo-N= N}- derivatives (Ar = C6H5, 4-FC6H4, 4-t-BuC6H4, 3,5-Me2C6H3, 3,5-Ph2C6H3, and 3,5-(4-t-BuC6H4) 2C6H3). Compounds that were crystallographically characterized include {[t-BuC6H4N3N]Mo}2 (N2), Na(THF)6{[PhN3N]Mo-N=N}2Na(THF)3, [t-BuC6H4N3N]Mo-N=N-Na(15-crown-5), and {[Ph2C6H3N3N]MoNN}2 Mg(DME)2. Compounds of the type [ArN3N]Mo-N=N-Mo[ArN3N] do not appear to form when Ar = 3,5-Ph2C6H3 or 3,5-(4t-BuC6H4)2C6H3, presumably for steric reasons. Treatment of diazenido complexes (eg., [ArN3N]Mo-N=NNa(THF)x) with electrophiles such as Me3SiCl or MeOTf yielded [ArN3N]Mo-N=NR complexes (R = SiMe3 or Me). These species react further to yield {[ArN3N]Mo-N=NMe2}+ species in the presence of methylating agents. Addition of anionic methyl reagents to {[ArN3N]Mo-N=NMe2}+ species yielded [ArN3N]Mo(N=NMe2)(Me) complexes. Reduction of [4-t-BuC6H4N3N]WCl under dinitrogen leads to a rare {[t-BuC6H4N3N]W}2(N2) species that can be oxidized by two electrons to give a stable dication (as its BPh4- salt). Reduction of hydrazido species leads to formation of MoN in low yields, and only dimethylamine could be identified among the many products. Electrochemical studies revealed expected trends in oxidation and reduction potentials, but also provided evidence for stable neutral dinitrogen complexes of the type. [ArN3N]Mo(N2) when Ar is a relatively bulky terphenyl substituent.