351026-98-7Relevant academic research and scientific papers
Grignard reactions of 4-substituted-2-keto-1,3-dioxanes: Highly diastereoselective additions controlled by a remote alkyl group
Bailey, William F.,Reed, David P.,Clark, Daniel R.,Kapur, Gabriel N.
, p. 1865 - 1867 (2007/10/03)
(matrix presented) The reactions of Grignard reagents with a representative series of simple cis-2-keto-4-substituted-1,3-dioxanes have been investigated. The stereochemical outcome of these highly diastereoselective additions (dr > 90:10) is consonant wi
