351386-46-4

Upstream product

• 113327-37-0 (2S)-isopropyl-2-<(tert-butyldimethylsilyl)oxy>-5-methyl-4-<(2-tetrahydropyran-2-yloxy)methyl>-4-hexenoate 
• 351386-44-2 isopropyl (2S)-2-hydroxy-5-methyl-4-[(2-tetrahydropyranyloxy)methyl]-4-hexenoate 
• 100-39-0 benzyl bromide 

Downstream Products

• 351386-33-9 ethyl (2Z,4S)-4-benzyloxy-6-hydroxymethyl-7-methyl-3-[(trimethylsilyl)methyl]octa-2,6-dienoate 
• 351386-50-0 ethyl (4S)-(2Z)-4-benzyloxy-3-(diethylphosphoryl)-7-methyl-6-[(2-tetrahydropyranyloxy)methyl]-2,6-octadienoate 
• 351386-58-8 ethyl (4S)-(2Z)-4-benzyloxy-7-methyl-6-[(2-tetrahydropyranyloxy)methyl]-3-[(trimethylsilyl)methyl]-2,6-octadienoate 
• 351386-48-6 ethyl (4S)-4-benzyloxy-7-methyl-3-oxo-6-[(2-tetrahydropyranyloxy)methyl]-6-octenoate 

Relevant academic research and scientific papers

Cyclizations versus rearrangements in the reactions of some epoxyolefins with Lewis acids

Treatment of various substituted epoxyolefins A with B F3·OEt2 and other reagents that could be expected to induce carbocyclization to give cyclohexanes was investigated. It turned out that the general reaction of these systems was t