351903-78-1

Basic information

• Product Name: (η5-indenyl)(CO)2Re(C(CCC6H4-p-CH3)(C6H4-p-N(CH3)2))
• CAS NO: 351903-78-1
• Molecular Weight: 604.722
• Mol File: 351903-78-1.mol

Chemical Properties

• CAS DataBase Reference: (η5-indenyl)(CO)2Re(C(CCC6H4-p-CH3)(C6H4-p-N(CH3)2))(CAS DataBase Reference)
• NIST Chemistry Reference: (η5-indenyl)(CO)2Re(C(CCC6H4-p-CH3)(C6H4-p-N(CH3)2))(351903-78-1)
• EPA Substance Registry System: (η5-indenyl)(CO)2Re(C(CCC6H4-p-CH3)(C6H4-p-N(CH3)2))(351903-78-1)

Safety Data

• Hazardous Substances Data: 351903-78-1(Hazardous Substances Data)

Upstream product

• 351903-78-1 (η5-indenyl)(CO)2Re(C(C6H4-p-CH3)(CCC6H4-p-N(CH3)2)) 

Downstream Products

• 351903-78-1 (η5-indenyl)(CO)2Re(C(CCC6H4-p-CH3)(C6H4-p-N(CH3)2)) 

Relevant articles and documents

[1,3]-metal shifts in rhenium alkynyl carbene complexes

The electron-withdrawing SO2CF3 substituent of Cp(CO)2Re=C(Tol)(C≡CC6H4-p-SO2 CF3) (1d) greatly accelerates rearrangement via a [1,3]-rhenium shift. The [1,3]-rhenium shift is proposed to proceed via an 18-electron dehydrometallacyclobutadiene intermediate formed by alkyne coordination concerted with an η5-η3 Cp ring slip.