351994-01-9Relevant academic research and scientific papers
Application of SiO 2 nanoparticles as an efficient catalyst to develop syntheses of perimidines and tetraketones
Alinezhad, Heshmatollah,Ahmadi, Armin,Hajiabbasi, Parvin
, (2019/04/10)
Abstract: In this paper, we explore the catalytic activity of SiO 2 nanoparticles (NPs) as an eco-friendly, efficient and reusable catalyst in the synthesis of 2,3-dihydro-1H-perimidines as well as tetraketones. For tetraketones syntheses, a si
Synthesis, Structure, and Biological Activities of 10-Substituted 3,3,6,6-Tetramethyl-9-Aryl-3,4, 6,7,9,10-hexahydroacridine-1,8(2H,5H)-dione Derivatives
Wang, Fang-Ming,Zhou, Lei,Li, Jun-Feng,Bao, Dan,Chen, Li-Zhuang
, p. 3120 - 3125 (2017/10/05)
A series of 10-substituted-3,3,6,6-tetramethyl-9-aryl-3,4,6,7,9,10-hexahydroacridine-1,8(2H,5 H)-dione derivatives 2 were synthesized by reaction of compounds 1 with amines. The compounds 1 were effectively prepared by 5,5-dimethylcyclohexane-1,3-dione an
Merging supramolecular catalysis and aminocatalysis: Amino-appended β-cyclodextrins (ACDs) as efficient and recyclable supramolecular catalysts for the synthesis of tetraketones
Ren, Yufeng,Yang, Bo,Liao, Xiali
, p. 22034 - 22042 (2016/03/08)
Well-designed amino-appended β-cyclodextrins (ACDs) with an amino side chain of different lengths at the primary face of β-CD were synthesized and employed in the catalytic synthesis of a series of tetraketones as supramolecular catalysts in water for the first time. Yields of 58-97% were obtained with up to 30 examples of substrate. The catalyst could be recycled easily, while a 92% yield and 84% rate of catalyst recovery could be achieved after 8 cycles of catalyst recycling. Moreover, a catalytic mechanism merging supramolecular catalysis and aminocatalysis could be proposed through detailed 1D and 2D NMR, ESI-MS and Job plot analyses. This protocol retained the promising characteristics of ambient temperature, green medium, simple operation, broad substrate scope, excellent yields, superb catalyst recycling performance and unique catalytic mechanism.
A four-ketone derivative and its preparation method and application
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Paragraph 0036; 0037; 0038, (2016/10/10)
The invention provides tetrone derivatives as well as a preparation method and application thereof. The derivatives have a general formula structure shown in the specification, wherein in the structure, R1 is any one of -H, 4-OCH3, 2-Cl, 3,4-(OCH3)2, 4-CH
An efficient and simple synthesis of tetraketones catalyzed by Yb(OTf) 3-sio2 under solvent free conditions
Kameshwara Rao,Kumar, Muthyala Manoj,Kumar, Anil
experimental part, p. 1128 - 1135 (2011/10/04)
A novel and efficient three-component one-pot condensation method has been described for the synthesis of tetraketones or arylmethylene[bis(3-hydroxy-2- cyclohexene-1-ones)] using Yb(OTf)3-SiO2 and amine as catalytic system under sol
A green and highly efficient protocol for catalyst-free Knoevenagel condensation and Michael addition of aromatic aldehydes with 1,3-cyclic diketones in PEG-400
Firouzeh, Nemati,Hossein, Kiani
experimental part, p. 2407 - 2410 (2012/02/04)
A convenient, highly efficient and green approach for synthesis of tetraketones from aromatic aldehydes with dimedone and 1,3-indanedione at room temperature in PEG-400 is described. The use of PEG-400 as the reaction medium and avoiding the use of any ca
