352020-91-8

Upstream product

• 67-56-1 methanol 
• 137344-41-3 3,4,5,7-tetra-O-benzyl-1-deoxy-α-D-gluco-hept-2-ulopyranose 
• 946847-85-4 ethyl 3,4,5,7-tetra-O-benzyl-1,2-dideoxy-2-thio-α-D-gluco-hept-2-ulopyranoside 
• 13096-62-3 (3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-6-((benzyloxy)methyl)tetrahydro-2H-pyran-2-one 

Downstream Products

• 352020-79-2 methyl O-(1'-C-methyl-2',3',4',6'-tetra-O-benzyl-α-D-glucopyranosyl)-(1'->6)-2,3,4-tri-O-benzyl-α-D-glucoside 

Relevant academic research and scientific papers

Synthesis of ketopyranosyl glycosides and determination of their anomeric configuration on the basis of the three-bond carbon-proton couplings

Anomeric pairs of ketopyranosyl glycosides with various substituents at Cα, Cβ and Cγ were synthesized from the corresponding thioglycosides, and the influence of the Cα-Cβ-Cγ-Hγ

A facile synthesis of 1′-C-alkyl-α-disaccharides from 1-C-alkyl-hexopyranoses and methyl 1-C-methyl-hexopyranosides

Direct O-glycosidations using the 1-C-alkyl-2,3,4,6-tetra-O-benzyl-hexopyranoses as the glycosyl donors were carried out with a catalytic amount (0.2 equiv.) of trimethylsilyl trifluoromethanesulfonate (TMSOTf). The glycosidations proceeded α-stereoselect