35211-83-7

Upstream product

• 108-31-6 maleic anhydride 
• 67-56-1 methanol 
• 629-20-9 1,3,5,7-cyclooctatetraene 
• 51447-09-7 endo-tricyclo<4.2.2.0^2,5>deca-3,9-diene-7,8-dicarboxylate anhydride 
• 186581-53-3 diazomethane 

Downstream Products

• 30286-95-4 3-phenyl-(3ac,3bt,7at,7bc)-3a,3b,4,5,6,7,7a,7b-octahydro-4r,7c-etheno-benzo[3,4]cyclobuta[1,2-d]isoxazole-5c,6c-dicarboxylic acid dimethyl ester 
• 75870-28-9 methyl (1RS,4SR,12RS)-4-phenylseleno-9-oxapentacyclo<6.4.0.0.^2,5.0^3,7.0^6,11>dodeca-10-one-12-carboxylate 
• 75870-19-8 dimethyl 3-exo-phenylseleno-4-endo-chloro-endo,endo-tricyclo<4.2.2.0^2,5>deca-9-ene-7,8-dicarboxylate 
• 77884-68-5 C₄₆H₄₈O₈ 
• 77884-68-5 C₄₆H₄₈O₈ 
• 127322-83-2 12,13-dimethoxycarbonyl-5-oxa-4-phenyl-6,6-phthaloyltetracyclo<7.2.2.0^2,80^3,7>tridec-10-ene 
• 68715-43-5 methyl (1RS,4SR,12RS)-4-phenylthio-9-oxapentacyclo<6.4.0.0.^2,5.0^3,7.0^6,11>dodeca-10-one-12-carboxylate 
• 58381-99-0 dimethyl 3-endo-chloro-4-exo-phenylthio-endo,endo-tricyclo<4.2.2.0^2,5>deca-9-ene-7,8-dicarboxylate 
• 62486-30-0 C₁₉H₁₆N₂O₈S 
• 68715-45-7 C₁₉H₁₆N₂O₈S 
• 78053-03-9 C₁₉H₁₇NO₆S 
• 68715-44-6 C₁₉H₁₇NO₆S 
• 68715-43-5 C₁₉H₁₈O₄S 
• 81061-48-5 cyclohexa-1,3-diene 

Relevant academic research and scientific papers

Electrophilic additions to strained alkenes. II. The reaction of benzeneselenenyl chloride with tricyclo2,5>deca-3,7-diene derivatives

The reactions of benzeneselenenyl chloride with three derivatives of tricyclo2,5>deca-3,7-diene have been investigated in four solvent systems: methylene chloride, acetic acid, acetic acid/LiClO4, and methanol.Under conditions of kinetic control only products of exo-anti attack upon the cyclobutene moiety are isolable when the solvent system is methylene chloride or acetic aicd.This observation also holds in acetic acid/LiClO4 except in the case of dimethyl tricyclo2,5>deca-3,7,9-triene-7,8-dicarboxylate where the major product is that of cross-bonding with solvent incorporation.In methanol products of solvent incorporation, transannular cross-bonding and lactonization (where possible) are observed.A general mechanistic scheme is proposed to account for these observations in accord with earlier results for the analogous arenesulphenylations.