352320-85-5

Basic information

• Product Name: benzyl chloro[(chlorocarbonyl)oxy]acetate
• Synonyms: benzyl chloro[(chlorocarbonyl)oxy]acetate
• CAS NO: 352320-85-5
• Molecular Weight: 263.077
• Mol File: 352320-85-5.mol

Chemical Properties

• CAS DataBase Reference: benzyl chloro[(chlorocarbonyl)oxy]acetate(CAS DataBase Reference)
• NIST Chemistry Reference: benzyl chloro[(chlorocarbonyl)oxy]acetate(352320-85-5)
• EPA Substance Registry System: benzyl chloro[(chlorocarbonyl)oxy]acetate(352320-85-5)

Safety Data

• Hazardous Substances Data: 352320-85-5(Hazardous Substances Data)

Upstream product

• 32315-10-9 bis(trichloromethyl) carbonate 
• 52709-42-9 benzylglyoxylate 

Downstream Products

• 352322-05-5 2-(benzoyloxy)-1-[(2,2-dimethylpropanoyl)oxy]-2-oxoethyl 2-benzoyl-2-tert-butyl-1-(4-chlorobenzoyl)hydrazinecarboxylate 
• 352321-51-8 [N'-benzoyl-N'-tert-butyl-N-(4-chloro-benzoyl)-hydrazinocarbonyloxy]-iodo-acetic acid benzyl ester 
• 353757-96-7 2-(benzyloxy)-1-chloro-2-oxoethyl 2-benzoyl-2-tert-butyl-1-(4-chlorobenzoyl)hydrazinecarboxylate 

Relevant articles and documents

Synthesis and application of novel glyoxylate-derived chloroformates

A convenient process for the synthesis of glyoxylate-derived chloroformates has been developed. The approach involves the reaction of glyoxylate esters with triphosgene and pyridine in various solvent systems. These novel glyoxylate-derived chloroformates are multifunctional, possessing a chloroformate, ester, and haloalkyl moiety. Further elaboration via a thiocarbonate route afforded highly functionalized carboxylic acid-derived alkoxycarbonyl-chlorocarbonyloxy-methyl esters. Application of a benzyl glyoxylate-derived chloroformate to halofenozide was also accomplished, affording halofenozide-N-carbonyloxy-chloro/iodoacetic acid benzyl ester derivatives, which-were further derivatized to carboxylic acid-derived (halofenozide-N-carbonyloxy)-benzyloxycarbonyl-methyl esters. The trifunctional nature of the glyoxylate moiety was demonstrated through conversion of the benzyloxycarbonyl moiety of a carboxylic acid-derived (halofenozide-N-carbonyloxy)-benzyloxycarbonyl-methyl ester to its respective diethylamide.

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