35278-89-8Relevant academic research and scientific papers
Allylation of n,n-acetal derivatives using allyl tin reagent in the presence of aluminum chloride
Sun, Xiaonan,Obu, Takanori,Kijima, Tatsuro,Murakami, Satoshi,Matsuba, Shigeru,Kusakari, Miho,Hatano, Bunpei
, p. 2395 - 2402 (2013/11/19)
Allylation of N,N-acetal derivatives proceeded efficiently using allyl tin regent in the presence of aluminum chloride, giving homoallylamines in good yields. This allylation was applied for N,S-acetals to give the corresponding homoallylamines.
Zinc-mediated allylation and alkylation of aminals in the presence of TMSCl and diisopropylamine
Hatano, Bunpei,Nagahashi, Keita,Kijima, Tatsuro
supporting information; scheme or table, p. 9188 - 9191 (2009/04/11)
(Chemical Equation Presented) An alkylation of aminals with organozinc reagents derived from allyl bromide, benzyl bromide, α-bromoacetate, and α-bromonitrile proceeded efficiently in the presence of TMSCl and diisopropylamine. This reaction system was applied to the synthesis of an antispasmodic: butaverine.
