35293-50-6

Basic information

• Product Name: 1,3-dimethyl-4-thiocyanatobenzene
• Synonyms: 1,3-dimethyl-4-thiocyanatobenzene
• CAS NO: 35293-50-6
• Molecular Weight: 163.243
• Mol File: 35293-50-6.mol

Chemical Properties

• CAS DataBase Reference: 1,3-dimethyl-4-thiocyanatobenzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3-dimethyl-4-thiocyanatobenzene(35293-50-6)
• EPA Substance Registry System: 1,3-dimethyl-4-thiocyanatobenzene(35293-50-6)

Safety Data

• Hazardous Substances Data: 35293-50-6(Hazardous Substances Data)

Upstream product

• 108-38-3 m-xylene 
• 1147550-11-5 ammonium thiocyanate 
• 13616-83-6 1,2-bis(2,4-dimethylphenyl)disulfane 
• 333-20-0 potassium thioacyanate 
• 95-68-1 2,4-Xylidine 

Downstream Products

• 13616-84-7 (2,4-dimethyl-phenyl)-(2,4-dinitro-phenyl)-sulfide 

Relevant articles and documents

N -Thiocyanato-dibenzenesulfonimide: A new electrophilic thiocyanating reagent with enhanced reactivity

A novel electrophilic thiocyanating reagent, N-thiocyanato-dibenzenesulfonimide, was prepared and exhibited enhanced electrophilicity with a wide scope of substrates. Thus, it reacted with activated aromatics such as phenols, indoles, anilines and anisoles without a catalyst giving the corresponding thicyanate derivatives in high yields, while TfOH for unactivated arenes and hetero aromatics and Zn(OTf)2 for ketones was used as the catalyst, respectively. It is noteworthy that internal alkenes and styrenes were bifunctionalized giving 1,2-amino thiocyanates in high yields.

Electrochemical ipso-Thiocyanation of Arylboron Compounds

An operationally simple electrochemical method for the transition-metal-free ipso-thiocyanation of arylboronic acids and aryl trifluoroborates has been developed. The SCN electrophile is generated in situ by anodic oxidation of thiocyanate anions, which avoids formation of salt waste and prevents unwanted side reactions arising from chemical oxidants. The reaction proceeds regiospecifically, and the scope extends to non-activated aromatic systems. (Figure presented.).

Practical access to aromatic thiocyanates by CuCN-mediated direct aerobic oxidative cyanation of thiophenols and diaryl disulfides

The practical and mild aerobic oxidative CuCN-mediated cyanation of thiophenols and diaryl disulfides was investigated. The reaction was performed in air at room temperature and reached aromatic thiocyanates in moderate to good yields starting from a broad range of diversely functionalized substrates.

Efficient and novel method for thiocyanation of aromatic compounds using trichloroisocyanuric acid/ammonium thiocyanate/wet SiO2

An efficient and novel method for thiocyanation of aromatic and heteroaromatic compounds using trichloroisocyanuric acid/ammonium thiocyanate/wet SiO2 is described. Copyright Taylor & Francis Group, LLC.

Anodic thiocyanation of mono-and disubstituted aromatic compounds

The in situ and environmentally friendly thiocyanation (no use of toxic oxidizing agents) electrochemical thiocyanation of aromatic compounds involving various derivatives of anisole and aniline to afford aromatic thiocyanates have been studied in organic