35310-85-1Relevant articles and documents
Molecular iodine-catalyzed benzylation of arenes with benzyl alcohols
Sun, Gaojun,Wang, Zhiyong
, p. 4929 - 4932 (2008/09/21)
A novel molecular iodine-catalyzed benzylation of arenes with benzyl alcohols has been developed. The reaction can be carried out under mild conditions to afford a series of diarymethane derivatives in high yields and good regioselectivities.
Catalysis of α-Fe and Fe1-xS toward the Hydrogenolysis of trans-Stilbene in Hydroaromatic Hydrocarbon Solvents
Futamura, Shigeru,Fujimoto, Ken-ichiro,Kamiya, Yoshio
, p. 2564 - 2568 (2007/10/02)
The Fe-catalyzed hydrogenolysis of trans-stilbene was carried out in aromatic hydrocarbon solvents at 380 deg C. α-Fe and pyrrhotite catalyze bimolecular hydrogen transfer from hydroaromatic hydrocarbons to trans-stilbene and hydroaromatic hydrocarbon-mediated hydrogenolysis of trans-stilbene by molecular hydrogen at 380 deg C.This catalyzed hydrogen transfer proceeds by radical mechanism.The product distribution is affected by the catalyst species.Pyrrhotite catalyzes the hydrogenation of trans-stilbene more effectively than α-Fe.Both the iron catalysts are inactive toward the cleavage of carbon to carbon single bond in bibenzyl.
THERMAL TRANSFER FLUID: 1-PHENYL-1-TETRAHYDRONAPHTHYLETHANE.
Matsumoto,Furukawa,Tanaka,Yano,Kamita
, p. 215 - 218 (2007/10/14)
Naphthalene was selectively hydrogenated to tetralin, followed by reaction with styrene to give 1-phenyl-1-tetrahydronaphthylethane in 87% yield. Efficient catalysts for the reaction were 90% sulfuric acid or solid acids possessing acid sites of H//0 less than or equal to minus 5. 6. Purified 1-phenyl-1-tetrahydronaphthylethane has favored properties for a high boiling point thermal transfer fluid: boiling point, 342 C; pour point minus 37. 5 C; good thermal stability, etc. On severe heating, it decomposed to low fractions to some extent with little tendency to polymerization.