35334-83-9Relevant academic research and scientific papers
Synthesis and double doping behavior of a poly(p-phenylenevinylene)s bearing conjugated side chains
Kawashima, Hirotsugu,Kawabata, Kohsuke,Goto, Hiromasa
, p. 1530 - 1538 (2012)
A poly(p-phenylenevinylene) derivative bearing conjugated side chains (polyCPV) was synthesized by Migita-Kosugi-Stille type coupling polycondensation reaction. This polymer contains phenylenevinylene units in both the main chain and the side chains. UV-vis absorption and fluorescence emission spectroscopies revealed a well-developed π-conjugation of the polyCPV. The absorption band of the polymer was extended to long wavelengths. A fluorescent emission maximum of polyCPV is located at considerably longer wavelengths than that of the conjugated side chain monomer. Electron spin resonance measurements of polyCPV confirmed generation of charge species in both the main chain and the side chains via iodine doping.
A stimuli-responsive and chemically tunable organic microcrystal laser switch
Cai, Xin,Xu, Zhenzhen,Zheng, Xiaolin,Ran, Chenhui,Liu, Peng,He, Xianxiong,Jin, Xue,Liao, Qing,Fu, Hongbing
, p. 814 - 817 (2019)
We demonstrated a stimuli-responsive and chemically switchable organic microbelt laser through reversible protonation-deprotonation reactions. The parent microbelt cavity together with the optically allowed 0-1 transition of H-aggregates enables a microlaser to operate at 585 nm. Upon HCl vapor treatment, the protonation of surface molecules shifts the lasing wavelength to 560 nm, generating an intensity contrast ratio >105, accompanied by a sharp color change from orange (deprotonated) to green (protonated). When treated with HCl-NH3 vapor, the protonation-deprotonation reactions lead to a reversible microlaser switch between 585 nm and 560 nm with good reproducibility and photostablity, making them attractive in high-throughput chemical and biological sensing applications.
ω,ω′-Dihetaryl-substituted 2,5-dimethyl-1,4-divinylbenzenes
Minakova,Bedrik,Shershukov
, p. 617 - 620 (1999)
A series of ω,ω′-dihetaryl-substituted 2,5-dimethyl-1,4-divinylbenzenes has been synthesized and these show an increased solubility when compared with analogs not containing methyl groups in the central benzene ring. The dependence of spectral parameters
Synthesis method of novel small organic molecule, preparation method of microcrystals and application
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Paragraph 0011, (2019/10/01)
The invention discloses a synthesis method of a novel small organic molecule, a preparation method of microcrystals and application. A new molecule 5PDA has the design thought that in order to obtain a small-molecule probe with acid and alkali response, t
NOVEL LIQUID CRYSTALLINE COMPOUND, LIQUID CRYSTAL COMPOSITION, OPTICAL ELEMENT AND OPTICAL DISPLAY DEVICE
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Paragraph 0096, (2018/10/16)
PROBLEM TO BE SOLVED: To provide a novel liquid crystalline compound that is low in dielectric anisotropy, has responsiveness, and changes its birefringence by application of voltage. SOLUTION: The present invention provides a compound represented by formula (1) (In the formula (1), R1, R2 and R3 independently represent a hydrogen atom or C1-C10 alkyl, in the alkyl, at least one -CH2- may be substituted by -O-, -S-, -CO-, or -SiH2-, and at least one -(CH2)2- may be substituted by -CH=CH-or -C≡C-. n is an integer of 0-4. m is an integer of 1 or 2. Z1 and Z2 are -CH=CH-). SELECTED DRAWING: None COPYRIGHT: (C)2016,JPOandINPIT
