35377-82-3Relevant academic research and scientific papers
Copper-catalyzed thiocarbonylation and thiolation of alkyl iodides
Tian, Qingqiang,Sun, Rongjing,Li, Yahui
supporting information, p. 1186 - 1190 (2022/02/19)
In the present study, an efficient Cu-catalyzed transthiolation of alkyl iodides is developed. Notably, in the presence of CO, thioesters could also be obtained with copper and cobalt as the co-catalyst. This transformation displayed good functional group
S,S-dimethyl dithiocarbonate: A novel carbonyl dication synthon in the synthesis of ketones
Chen, Chiar-Dy,Huang, Jui-Wen,Leung, Man-Kit,Li, Huei-Hsu
, p. 9067 - 9078 (2007/10/03)
We report herein the use of DMDTC as an effective carbonyl dication equivalent in ketone synthesis. According to our strategy, we also successfully devised a synthetic pathway for S-methyl (trimethylsilyl)thioacetate which may be a potentially useful synthetic reagent in organic synthesis.
DIMETHYLALUMINIUM METHANESELENOLATE - A USEFUL REAGENT FOR THE PREPARATION OF SELENOESTERS. A NEW FRIEDEL-CRAFTS ACYLATION PROCEDURE PROMOTED BY Cu(I)
Kozikowski, Alan P.,Ames, Anthony
, p. 4821 - 4834 (2007/10/02)
The preparation of a new aluminium reagent, dimethylaluminium methaneselenolate (Me2AlSeMe) is described.The reactivity of this aluminium reagent toward a variety of organic substrates has been studied.Me2AlSeMe will convert O-alkyl esters to selenoesters in high yield.These selenoesters function as extremely reactive acyl transfer agents and are converted to acids, esters, and amides on reaction with water, alcohols or amines in the presence of a selenophilic metal cation.The selenoesters will, moreover, acylate reactive arenes and heterocyclic compounds when cuprous triflate is employed as the selenophilic metal cation.This latter transformation constitutes a new transition metal promoted variant of the Friedel-Crafts acylation reaction.
