354797-79-8

Upstream product

• 152420-91-2 1-O,2-S-(2-acetyl-1-methyl-1,2-ethenediyl)-3,4,6-tri-O-benzyl-2-thio-α-D-glucopyranose 
• 67-63-0 isopropyl alcohol 
• 196078-43-0 Acetic acid 1-((4aR,6R,7R,8S,8aR)-7,8-bis-benzyloxy-6-benzyloxymethyl-3-methyl-6,7,8,8a-tetrahydro-4aH-4,5-dioxa-1-thia-naphthalen-2-yl)-ethyl ester 

Relevant academic research and scientific papers

Versatile intermediate for complete α/β stereocontrol in O-glycosidation reactions

β-O-Glucosides 5, which can be completely converted to the α-anomers in the reaction medium, are obtained as single isomers by glycosidation of readily available donor 1 and are easily transformed into 2-deoxy-β-O-glucosides.

Stereoselective 2-deoxy-β-O-glycoside synthesis based on remote activation of novel oxathiine donors

Stable glyco-fused 1,4-oxathiine derivatives, prepared by inverse electron-demand Diels-Alder reactions between suitable 1-glycals and 3-thioxopentane-2,4-dione, have been transformed into unusual glycosyl donors which, after "remote activation", react ef