35491-40-8Relevant academic research and scientific papers
Action of (2-Benzothiazolyl) Methyllithium with Organic Polar Functions
Costa, Maria Virginia,Brembilla, Alain,Roizard, Denis,Lochon, Pierre
, p. 1541 - 1544 (2007/10/02)
(2-Benzothiazolyl) methyllithium reacts quickly at low temprature (-78 deg C) with a variety of organic electrophiles like aldehydes, ketones, carboxylic esters, nitriles and acylchlorides.Such reactions lead to an easy introduction of alcohol, keto-enol
Action of (2-Benzothiazolyl)methyllithium with Organic Polar Functions
Costa, Maria Virginia,Brembilla, Alain,Roizard, Denis,Lochon, Pierre
, p. 1933 - 1936 (2007/10/02)
(2-Benzothiazolyl)methyllithium reacts quickly at low temperature (-78 deg C) with a variety of organic electrophiles like aldehydes, ketones, carboxylic esters, nitriles and acyl chlorides.Such reactions lead to an easy introduction of alcohol, keto-enol or amine-enamine functional groups in extracyclic position with a stereoselective preference.These polyfunctional compounds whose synthesis is difficult by other pathways, are interesting, in particular, because of their ability to form intramolecular hydrogen bounds.
General Method for an Aldol-Type Reaction of 2-Methylbenzothiazole with Carbonyl Compounds
Chikashita, Hidenori,Ikegami, Seiji,Okumura, Takeshi,Itoh, Kazuyoshi
, p. 375 - 377 (2007/10/02)
A general and versatile method for the preparation of a variety of β-hydroxybenzothiazoles (aldol-type adducts) by the reaction of α-lithio-2-methylbenzothiazole with carbonyl compounds was proposed.As an example of the use of α-lithio-2-methylbenzothiazo
