355-73-7Relevant academic research and scientific papers
PROCESS FOR PRODUCING FLUORINE-CONTAINING ALIPHATIC AMINE HYDROCHLORIDE
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Paragraph 0046, (2018/06/30)
PROBLEM TO BE SOLVED: To provide a production process in which a high purity fluorine-containing aliphatic amine hydrochloride can be produced efficiently. SOLUTION: Provided is a process for producing fluorine-containing aliphatic amine hydrochloride comprising a step (I) in which hydrogen chloride (B) is acted on a fluorine-containing aliphatic amine (A) in a solution (X) containing (A), (B) and water to produce a fluorine-containing aliphatic amine hydrochloride (C), and a step (II) in which, after step (I), (C) is subjected to solid-liquid separation, and an aqueous solution (F) in which (C) is dissolved in water and a solution (G) containing hydrogen chloride (B) are mixed to make a solution (H), followed by precipitating (C) in the solution (H), and in which, characterized, the concentration of hydrogen chloride (B) in the solution (H) immediately after mixing the aqueous solution (F) and the solution (G) is 8 to 20 wt.% based on the weight of (H). SELECTED DRAWING: None COPYRIGHT: (C)2018,JPO&INPIT
Synthesis and phosphonate binding of guanidine-functionalized fluorinated amphiphiles
Wu, Xinping,Boz, Emine,Sirkis, Amy M.,Chang, Andy Y.,Williams, Travis J.
experimental part, p. 292 - 302 (2012/03/27)
We report herein convenient procedures for the use of highly fluorinated α,ω-diols (e.g. 1) as building blocks for the rapid assembly of amphiphilic materials containing a fluorous phase region. We describe expedient conversion of the parent diols to both
Synthesis and characterization of highly fluorinated diamines and benzoxazines derived therefrom
Velez-Herrera, Pedro,Ishida, Hatsuo
experimental part, p. 573 - 580 (2009/11/30)
A novel method for the synthesis of highly fluorinated benzoxazines in a high yield derived form a α,ω-diamine-polyfluoroalkane and α,ω-dianiline-polyfluoroalkane is described. The synthetic method increases the yield by 20% and reduces the reaction time
Highly fluorinated diazides and process therefor
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, (2008/06/13)
This invention relates to highly fluorinated diazides of the formula N3 CH2 (CF2)x CH2 N3 wherein x is a positive integer from 2 to 12; to the preparation of these diazides by the reaction of excess sodium azide with a ditosylate of the formula C7 H7 SO3 CH2 (CF2)x CH2 O3 SC7 H7 wherein x has the same meaning given above; and to the synthesis of highly fluorinated primary diamines of the formula H2 NCH2 (CF2)x CH2 NH2 wherein x has the same meaning given above by catalytic hydrogenation of said diazides.
