355118-34-2Relevant academic research and scientific papers
Synthesis and Structure of 1,2-Dimethylene[2.10]metacyclophane and Its Conversion into Chiral [10]Benzenometacyclophanes
Akther, Thamina,Islam, Md. Monarul,Matsumoto, Taisuke,Tanaka, Junji,Thuéry, Pierre,Redshaw, Carl,Yamato, Takehiko
, p. 1721 - 1726 (2017)
Bromination of 5,21-di-tert-butyl-8,24-dimethoxy-1,2-dimethyl[2.10]metacyclophan-1-ene (MCP-1-ene; 1) with benzyltrimethylammonium tribromide exclusively afforded 1,2-bis(bromomethyl)-5,21-di-tert-butyl-8,24-dimethoxy[2.10]MCP-1-ene (2). Debromination of
Medium-sized cyclophanes. Part 57. Synthesis, conformations and stereodynamics of [2.n] metacyclophan-1-enes and their conversion to [2.n] metacyclophan-1-ynes
Yamato,Fujita,Abe,Tsuzuki
, p. 728 - 736 (2007/10/03)
anti- and syn-[2.8]Metacyclophan-1-enes 3a, which are both conformationally rigid structures, were prepared in good yields by a McMurry cyclization of 1,8-bis(5-tert-butyl-3-formyl-2-methoxyphenyl)octane 2a. Similarly, McMurry cyclization of 1,10-bis(5-te
