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Tri-m-tolyl-stibane is a chemical compound with the formula (m-tolyl)3Sb, where m-tolyl represents the methyl group attached to the meta position of the tolyl group. This organostibane compound is characterized by its three m-tolyl groups bonded to a central antimony atom. It is an organometallic compound, which means it contains a carbon-metal bond, and is part of a class of compounds that are of interest in materials science and organometallic chemistry. Tri-m-tolyl-stibane and its derivatives are studied for their potential applications in various fields, including as precursors in the synthesis of other organostibane compounds and in the development of new materials with unique properties.

35569-54-1

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35569-54-1 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 35569-54-1 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,5,5,6 and 9 respectively; the second part has 2 digits, 5 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 35569-54:
(7*3)+(6*5)+(5*5)+(4*6)+(3*9)+(2*5)+(1*4)=141
141 % 10 = 1
So 35569-54-1 is a valid CAS Registry Number.

35569-54-1Relevant academic research and scientific papers

Fourier-transform Raman and infrared spectra and normal coordinate analysis of the triphenyl compounds and their methyl-, methoxy- and fluoro-substituted derivatives of arsenic, antimony and bismuth

Ludwig,Dolny,Goetze

, p. 2363 - 2372 (2007/10/03)

The Fourier transform (FT)-Raman and infrared (IR) spectra of triphenyl-, perdeuterated triphenyl-, tris(2-methylphenyl)-, tris(3-methylphenyl)-, tris(2,4,6-trimethylphenyl)-, tris(2-methoxyphenyl)-, tris(3-methoxyphenyl)-, tris(3-fluorophenyl)- and tris(

Syntheses, Structures, and Equilibria of o-, m-, p-Tolyl- and Phenylantimony Rings

Breunig, Hans Joachim,Ebert, Klaus Heinz,Guelec, Sabahittin,Probst, Joachim

, p. 599 - 604 (2007/10/02)

Exchange reactions of R3Sb (R = o-Tol, m-Tol, p-Tol) with SbCl3 in a 1:2 molar ratio give RSbCl2.Silylstibanes RSb(SiMe3)2 were obtained by reaction of RSbCl2 and Me3SiCl with Mg in THF.Slow access of air to solutions of RSb(SiMe3)2 afforded orange crystals of the composition (RSb)n.Crystal structures were determined by X-ray crystallography fro R = o-Tol and m-Tol as stacks of (RSb)6 rings in the chair conformation with equatorial substituents.In the crystals of (m-TolSb)6 there are short intermolecular Sb***Sb distances of 420 pm.Solutions of (RSb)n (R = Ph, o-Tol, m-Tol, p-Tol) in C6D6 were analyzed by 1H-NMR spectroscopy.They contain (RSb)5 and (RSb)4 in equilibria.Raman spectra of (PhSb)6 or (p-TolSb)n show signals for Sbn at = 151 or 153 cm-1. 13C-CP-MAS-NMR data of (p-TolSb)n are reported. - Key Words: Cyclopentastibanes/ Cyclohexastibanes/ Antimony compounds/ Phenylantimony rings

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